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A mineral having the formula AB(2) cryst...

A mineral having the formula `AB_(2)` crystallizes in the `ccp` lattice, with `A` atoms occupying the lattice points. Select the correct statement(s).

A

The coordination number `(CN)` for `A` atoms `= 8`.

B

The `CN` for `B` atom `= 4`

C

`100%` of `TV_(s)` are occupied by `B` atoms

D

`50%` of `TV_(s)` are occupied by `B` atoms.

Text Solution

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To solve the problem regarding the mineral with the formula \( AB_2 \) that crystallizes in a cubic close-packed (ccp) lattice, we will follow these steps: ### Step-by-Step Solution: 1. **Understanding the ccp Lattice**: - The cubic close-packed (ccp) structure is also known as face-centered cubic (fcc). In an fcc lattice, there are 4 atoms per unit cell. 2. **Identifying the Atoms**: - In the given formula \( AB_2 \), \( A \) occupies the lattice points, and \( B \) occupies the voids. Since \( A \) occupies the lattice points, the number of \( A \) atoms in the unit cell is 4 (as there are 4 atoms per fcc unit cell). 3. **Calculating the Number of \( B \) Atoms**: - The formula \( AB_2 \) indicates that for every 1 atom of \( A \), there are 2 atoms of \( B \). Therefore, if there are 4 atoms of \( A \), the number of \( B \) atoms will be: \[ \text{Number of } B = 2 \times \text{Number of } A = 2 \times 4 = 8 \] 4. **Coordination Numbers**: - In a ccp lattice, the coordination number of \( A \) atoms (which are at the lattice points) is 8. This means each \( A \) atom is surrounded by 8 other atoms. - The coordination number of \( B \) atoms, which occupy tetrahedral voids, is 4. Each \( B \) atom is surrounded by 4 \( A \) atoms. 5. **Tetrahedral Voids**: - In a ccp lattice, there are 8 tetrahedral voids per unit cell. Since we have 8 \( B \) atoms, it means that all the tetrahedral voids are occupied by \( B \) atoms. - Therefore, 100% of the tetrahedral voids are occupied by \( B \) atoms. ### Summary of Findings: - Coordination number for \( A \) atoms = 8 (Option A is correct). - Coordination number for \( B \) atoms = 4 (Option B is correct). - 100% of tetrahedral voids are occupied by \( B \) atoms (Option C is correct). - Option D (50% of tetrahedral voids occupied) is incorrect. ### Final Answer: - Options A, B, and C are correct.

To solve the problem regarding the mineral with the formula \( AB_2 \) that crystallizes in a cubic close-packed (ccp) lattice, we will follow these steps: ### Step-by-Step Solution: 1. **Understanding the ccp Lattice**: - The cubic close-packed (ccp) structure is also known as face-centered cubic (fcc). In an fcc lattice, there are 4 atoms per unit cell. 2. **Identifying the Atoms**: ...
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