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In a cubic,A atoms are present on altern...

In a cubic,`A` atoms are present on alternative corners, `B` atoms are present on alternate faces, and `C` atoms are present on alternalte edges and body centred of the cube. The simplest formula of the compound is

A

`A_(2)BC_(4)`

B

`AB_(2)C_(4)`

C

`ABC_(4)`

D

`ABC_(2)`

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To find the simplest formula of the compound with the given arrangement of atoms in a cubic structure, we will analyze the contributions of each type of atom (A, B, and C) based on their positions in the cube. ### Step-by-Step Solution: 1. **Identify the Contribution of A Atoms:** - A atoms are present at alternate corners of the cube. - A cube has 8 corners, but since A atoms are at alternate corners, we only consider 4 corners. - Each corner contributes \( \frac{1}{8} \) of an atom. - Therefore, the total contribution from A atoms is: \[ \text{Total A} = 4 \text{ corners} \times \frac{1}{8} = \frac{4}{8} = \frac{1}{2} \] 2. **Identify the Contribution of B Atoms:** - B atoms are present on alternate faces of the cube. - A cube has 6 faces, but B atoms occupy alternate faces, which gives us 3 faces. - Each face contributes \( \frac{1}{2} \) of an atom. - Therefore, the total contribution from B atoms is: \[ \text{Total B} = 3 \text{ faces} \times \frac{1}{2} = \frac{3}{2} \] 3. **Identify the Contribution of C Atoms:** - C atoms are present on alternate edges and at the body center of the cube. - A cube has 12 edges, and considering alternate edges gives us 6 edges. - Each edge contributes \( \frac{1}{4} \) of an atom. - The body center contributes 1 full atom. - Therefore, the total contribution from C atoms is: \[ \text{Total C} = 6 \text{ edges} \times \frac{1}{4} + 1 \text{ (body center)} = \frac{6}{4} + 1 = \frac{3}{2} + 1 = \frac{5}{2} \] 4. **Combine the Contributions:** - Now we have: - Total A = \( \frac{1}{2} \) - Total B = \( \frac{3}{2} \) - Total C = \( \frac{5}{2} \) 5. **Simplify the Formula:** - To find the simplest formula, we can multiply all contributions by 2 to eliminate the fractions: \[ A: \frac{1}{2} \times 2 = 1 \quad \Rightarrow A^1 \] \[ B: \frac{3}{2} \times 2 = 3 \quad \Rightarrow B^3 \] \[ C: \frac{5}{2} \times 2 = 5 \quad \Rightarrow C^5 \] - Therefore, the simplest formula of the compound is: \[ AB^3C^5 \] ### Final Answer: The simplest formula of the compound is \( AB^3C^5 \).

To find the simplest formula of the compound with the given arrangement of atoms in a cubic structure, we will analyze the contributions of each type of atom (A, B, and C) based on their positions in the cube. ### Step-by-Step Solution: 1. **Identify the Contribution of A Atoms:** - A atoms are present at alternate corners of the cube. - A cube has 8 corners, but since A atoms are at alternate corners, we only consider 4 corners. - Each corner contributes \( \frac{1}{8} \) of an atom. ...
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CENGAGE CHEMISTRY ENGLISH-SOLID STATE-Ex 1.1 (Objective)
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  2. In the body centered cubic unit cell and simple unit cell, the radius...

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  3. Which of the following expression is correct in case of a sodium chlor...

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  4. In silicon crystal, Si atoms from fcc arrangement where 4 out 8 TVs ar...

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  5. Which of the following crystal systems exist in bcc, end-centred, fcc,...

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  6. In a cubic,A atoms are present on alternative corners, B atoms are pre...

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  7. The fraction of octahedral voids filled by Al^(3+) ion in Al(2)O(3)(r(...

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  8. In the closet packing of atoms, there are:

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  9. Which of the following statements is correct in the body centred type ...

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  10. Aluminium metal has a density of 2.72 g cm^(-3) and crystallizes in a ...

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  11. If atoms are removed from half of the edge-centred OV(s) in RbBr, then...

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  12. ThO(2) exists in fluorite structure, what is the effective number of b...

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  13. What is the coordination number of Th^(4+) in ThO(2)?

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  14. The coordination number Cs and Br in CsBr are, respectively,

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  15. The fraction of the total volume occupied by the atoms present in a si...

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  16. Xenon crystallises in face - centered cubic , and the edge of the unit...

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  17. In BeO (zinc blende structure), Mg^(2+) is introduced in available TV ...

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  18. If the ions are removed from a single body diagonal in above case afte...

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  19. In spinel, Mg^(2+) is present in one-eighth of TVs in an fcc lattice o...

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