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Vapour pressure of pure A(p(A)^(@))=100 ...

Vapour pressure of pure `A(p_(A)^(@))=100` mm Hg
Vapour pressure of pure `B(p_(B)^(@))= 150` mm Hg
2 mol of liquid A and 3 mol of liquid B are mixed to form an ideal solution. The vapour pressure of solution will be:

A

`a.) 185 mm`

B

`b.) 130 mm`

C

`c.) 148 mm`

D

`d.) 145 mm`

Text Solution

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The correct Answer is:
To find the vapor pressure of the solution formed by mixing 2 moles of liquid A and 3 moles of liquid B, we can use Raoult's Law. Here are the steps to solve the problem: ### Step 1: Identify the given data - Vapor pressure of pure A, \( P^0_A = 100 \, \text{mm Hg} \) - Vapor pressure of pure B, \( P^0_B = 150 \, \text{mm Hg} \) - Moles of A, \( n_A = 2 \) - Moles of B, \( n_B = 3 \) ### Step 2: Calculate the total moles in the solution Total moles \( n_{total} = n_A + n_B = 2 + 3 = 5 \) ### Step 3: Calculate the mole fractions of A and B - Mole fraction of A, \( X_A = \frac{n_A}{n_{total}} = \frac{2}{5} \) - Mole fraction of B, \( X_B = \frac{n_B}{n_{total}} = \frac{3}{5} \) ### Step 4: Apply Raoult's Law According to Raoult's Law, the total vapor pressure of the solution \( P_{total} \) is given by: \[ P_{total} = P^0_A \cdot X_A + P^0_B \cdot X_B \] ### Step 5: Substitute the values into the equation Substituting the known values: \[ P_{total} = (100 \, \text{mm Hg} \cdot \frac{2}{5}) + (150 \, \text{mm Hg} \cdot \frac{3}{5}) \] ### Step 6: Calculate the individual contributions Calculating the contributions: - Contribution from A: \[ 100 \cdot \frac{2}{5} = 40 \, \text{mm Hg} \] - Contribution from B: \[ 150 \cdot \frac{3}{5} = 90 \, \text{mm Hg} \] ### Step 7: Find the total vapor pressure Now, add the contributions from A and B: \[ P_{total} = 40 \, \text{mm Hg} + 90 \, \text{mm Hg} = 130 \, \text{mm Hg} \] ### Final Answer The vapor pressure of the solution will be \( P_{total} = 130 \, \text{mm Hg} \). ---

To find the vapor pressure of the solution formed by mixing 2 moles of liquid A and 3 moles of liquid B, we can use Raoult's Law. Here are the steps to solve the problem: ### Step 1: Identify the given data - Vapor pressure of pure A, \( P^0_A = 100 \, \text{mm Hg} \) - Vapor pressure of pure B, \( P^0_B = 150 \, \text{mm Hg} \) - Moles of A, \( n_A = 2 \) - Moles of B, \( n_B = 3 \) ...
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