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The ebullioscopic constant for benzene i...

The ebullioscopic constant for benzene is `2.52 K Kg mol^(-1)`. A solution of an organic substance in benzene boils at `0.125^(@)C` higher than benzene. Calculate the molality of solution?

A

10

B

1

C

2

D

0.05

Text Solution

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The correct Answer is:
To solve the problem, we need to calculate the molality of a solution given the elevation in boiling point and the ebullioscopic constant of benzene. ### Step-by-Step Solution: 1. **Identify the given values:** - Ebullioscopic constant (Kb) for benzene = 2.52 K kg mol^(-1) - Elevation in boiling point (ΔTb) = 0.125 °C 2. **Use the formula for elevation in boiling point:** The formula relating the elevation in boiling point to molality is given by: \[ \Delta T_b = K_b \cdot m \] where: - ΔTb = elevation in boiling point - Kb = ebullioscopic constant - m = molality of the solution 3. **Rearrange the formula to solve for molality (m):** \[ m = \frac{\Delta T_b}{K_b} \] 4. **Substitute the known values into the equation:** \[ m = \frac{0.125 \, \text{°C}}{2.52 \, \text{K kg mol}^{-1}} \] 5. **Calculate the molality:** \[ m = \frac{0.125}{2.52} \approx 0.0496 \, \text{mol/kg} \] 6. **Round the answer to two decimal places:** \[ m \approx 0.05 \, \text{mol/kg} \] ### Final Answer: The molality of the solution is approximately **0.05 mol/kg**.

To solve the problem, we need to calculate the molality of a solution given the elevation in boiling point and the ebullioscopic constant of benzene. ### Step-by-Step Solution: 1. **Identify the given values:** - Ebullioscopic constant (Kb) for benzene = 2.52 K kg mol^(-1) - Elevation in boiling point (ΔTb) = 0.125 °C ...
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