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The electrolyte solutions show abnormal ...

The electrolyte solutions show abnormal colligative porperties.To account for this effect we define a quantity called the Van't Hoff factor given by
`i=("Actual number of particles in solution after dissociation")/("Number of formula units initially dissolved in solution")`
`i=1 ("for non-electrolytes")`
`igt1 ("for electrolytes, undergoing dissociation")`
`ilt1 ("for solutes, undergoing association")`
Answer the following questions:
A solution of benzoic acid is dissolved in benzene such that it undergoes molecular association and its molar mass apporaches `244`. The benzoic molecules will exist as

A

Dimer

B

Monomer

C

Tetramer

D

Trimer

Text Solution

Verified by Experts

The correct Answer is:
A

Molecular mass of benzoic acid =154
Molecular mass of associated molecule =244
`:. N=244//154 =1.6 ~~ 2`
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The electrolyte solutions show abnormal colligative porperties.To account for this effect we define a quantity called the Van't Hoff factor given by i=("Actual number of particles in solution after dissociation")/("Number of formula units initially dissolved in solution") i=1 ("for non-electrolytes") igt1 ("for electrolytes, undergoing dissociation") ilt1 ("for solutes, undergoing association") Answer the following questions: For a solution of a non-electrolyte in water, the Van't Hoff factor is

The electrolyte solutions show abnormal colligative porperties.To account for this effect we define a quantity called the Van't Hoff factor given by i=("Actual number of particles in solution after dissociation")/("Number of formula units initially dissolved in solution") i=1 ("for non-electrolytes") igt1 ("for electrolytes, undergoing dissociation") ilt1 ("for solutes, undergoing association") Answer the following questions: Benzoic acid undergoes dimerization in bezene solution. The Van't Hoff factor i for the solutions is

The electrolyte solutions show abnormal colligative porperties.To account for this effect we define a quantity called the Van't Hoff factor given by i=("Actual number of particles in solution after dissociation")/("Number of formula units initially dissolved in solution") i=1 ("for non-electrolytes") igt1 ("for electrolytes, undergoing dissociation") ilt1 ("for solutes, undergoing association") Answer the following questions: 0.1 M K_(4)[Fe(CN)_(6)] is 60% ionized. What will be its Van't Hoff factor?

The electrolyte solutions show abnormal colligative porperties.To account for this effect we define a quantity called the Van't Hoff factor given by i=("Actual number of particles in solution after dissociation")/("Number of formula units initially dissolved in solution") i=1 ("for non-electrolytes") igt1 ("for electrolytes, undergoing dissociation") ilt1 ("for solutes, undergoing association") Answer the following questions: certain substances trimerize when dissolved in a solvent A . The Van't Hoff factor i for the solutions is

van't Hoff factor more than unity indicates that the solute in solution has

The van't Hoff factor i for an electrolyte which undergoes dissociation in one solvent and association in other solvent respectively:

The Van't Hoff factor for a solute which does not dissociate or associate in solution is

In association of solute, the Van't Hoff factor is greater than unity.

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CENGAGE CHEMISTRY ENGLISH-SOLUTIONS-Exercises (Linked Comprehension)
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  2. The electrolyte solutions show abnormal colligative porperties.To acco...

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  3. The electrolyte solutions show abnormal colligative porperties.To acco...

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  8. Compartment A and B have the following combinations of solution: {:(...

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  9. The boiling point elevation and freezing point depression of solution...

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  11. The boiling point elevation and freezing point depression of solution...

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  12. The boiling point elevation and freezing point depression of solution...

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