Home
Class 12
CHEMISTRY
The EMF of the cell : Ag|AgCl,0.1 MKCl...

The `EMF` of the cell `:`
`Ag|AgCl,0.1 MKCl||0.1 M AgNO_(3)|Ag` is `0.45V. 0.1 M KCl `is `85%` dissociated and `0.1 M AgNO_(3)` is `82%` dissociated. Calculate the solubility product of `AgCl` at `25^(@)C`.

Text Solution

AI Generated Solution

To calculate the solubility product (Ksp) of AgCl at 25°C using the given data, we can follow these steps: ### Step 1: Determine the Concentrations of Ions We are given the dissociation percentages of KCl and AgNO3, which will help us find the concentrations of Cl⁻ and Ag⁺ ions. - For KCl (0.1 M, 85% dissociated): \[ [Cl^-] = 0.1 \, \text{M} \times \frac{85}{100} = 0.085 \, \text{M} ...
Promotional Banner

Topper's Solved these Questions

  • ELECTROCHEMISTRY

    CENGAGE CHEMISTRY ENGLISH|Exercise Solved Examples(Electrolysis And Electrolytic Cells)|12 Videos
  • ELECTROCHEMISTRY

    CENGAGE CHEMISTRY ENGLISH|Exercise Ex 3.1 (Objective)|28 Videos
  • ELECTROCHEMISTRY

    CENGAGE CHEMISTRY ENGLISH|Exercise Archieves Subjective|35 Videos
  • D AND F BLOCK ELEMENTS

    CENGAGE CHEMISTRY ENGLISH|Exercise Archives Subjective|29 Videos
  • GENERAL PRINCIPLES AND PROCESS OF ISOLATION OF ELEMENTS

    CENGAGE CHEMISTRY ENGLISH|Exercise Archives (Subjective)|14 Videos

Similar Questions

Explore conceptually related problems

The emf of the cell Ag|KI(0.05M)||AgNO_(3)(0.05M)|Ag is 0.788V . Calculate the solubility product of AgI .

EMF of the cell |Ag|AgNO_(3)(0.1M)||K Br(1 N),AgBr(s)|Ag is -0.6V at 298K AgNO_(3) is 80% and KBr is 60% dissociated. Calculate a. Solubility and b. K_(sp) of AgBr at 298 K .

The e.m.f of cell Ag|AgI_((s)),0.05M KI|| 0.05 M AgNO_(3)|Ag is 0.788 V . Calculate solubility product of AgI .

A weak acid HA is found to be 3% dissociated in 0.1 M solution . Calculate the value of K_a

Calculate the pH value of 0.01 M CH_3COOH if it is 5% dissociated.

Solubility of AgCl in 0.2 M NaCl is x and that in 0.1 M AgNO_(3) is y. Then which of the following is correct?

The EMF of the cell : Ag|Ag_(2)CrO_(4)(s),K_(2)CrO_(4)(0.1 M)||AgNO_(3)(0.1M)||Ag is 206.5mV. Calculate the solubility of Ag_(2)CrO_(4) in 1M Na_(2)CrO_(4) solution.

What will be the solubility of AgCl in 0.05 M NaCl aqueous solution if solubility product of AgCl is 1.5xx10^(-10) ?

Ag(s)|AgCl("saturated salt") KCl(C=0.025)||KNO_(3),AgNO_(3)(C=0.2)|Ag The emf of above cell is 0.43 V (a) write down the cell reaction (b) calculate the solubility product of AgCI

Predict if there will be any precipitate by mixing 50 mL of 0.01 M NaCl and 50 mL of 0.01 M AgNO_(3) solution. The solubility product of AgCl is 1.5xx10^(-10) .

CENGAGE CHEMISTRY ENGLISH-ELECTROCHEMISTRY-Solved Examples (Electrochemical Cell)
  1. The standard potential of a cell using the reaction is 1.12. The heat...

    Text Solution

    |

  2. The standard potential of a cell using the reaction +3HgO(s)+2(overse...

    Text Solution

    |

  3. The EMF of the cell : Ag|AgCl,0.1 MKCl||0.1 M AgNO(3)|Ag is 0.45V. 0...

    Text Solution

    |

  4. Calculate the potential corresponding to the following cell. Given P...

    Text Solution

    |

  5. Estimate the E^(@) reduction for Cu|CuS electrode. Given : K(sp) of...

    Text Solution

    |

  6. Knowing that K(sp) for AgCl is 1.0 xx 10^(-10), calculate E for a silv...

    Text Solution

    |

  7. Consider the following half reactions : PbO(2)(s)+4H^(o+)(aq)+SO(4)...

    Text Solution

    |

  8. The e.m.f of cell Ag|AgI((s)),0.05M KI|| 0.05 M AgNO(3)|Ag is 0.788 V....

    Text Solution

    |

  9. For the cell Zn|ZnCl(2)(m)|AgCl,E is 1.24V at 25^(@)C and 1.260V at 35...

    Text Solution

    |

  10. A saturated calomel electrode is coupled through a salt bridge with a ...

    Text Solution

    |

  11. Two weak acid solutions HA(1) and HA(2) with the same concentration an...

    Text Solution

    |

  12. Find the solubility of AgCl in 0.1 M CaCl(2). E^(c-).(Ag^(o+)|Ag)=0.79...

    Text Solution

    |

  13. The EMF of the cell : Ag|Ag(2)CrO(4)(s),K(2)CrO(4)(0.1 M)||AgNO(3)(0...

    Text Solution

    |

  14. The EMF of a galvanic cell Pt|H(2)(1 atm)|HCl(1M)|Cl(2)(g)|Pt is 1.29V...

    Text Solution

    |

  15. Calculate the potential of silver electrode in a saturated solution of...

    Text Solution

    |

  16. A solution of Fe^(2+) is titrated potentiaometrically using Ce^(4+) so...

    Text Solution

    |

  17. Find the EMF of the cell at 25^(@)C. E^(c-).(red("quinhydrone elec...

    Text Solution

    |

  18. Construct a cell using given electrodes at 298K and also calculate its...

    Text Solution

    |

  19. The EMF of the following cell is observed to be 0.118V at 25^(@)C: ...

    Text Solution

    |

  20. Find the standard electrode potential of I(2)|2I^(c-) if the equilibri...

    Text Solution

    |