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A solution of Fe^(2+) is titrated potent...

A solution of `Fe^(2+)` is titrated potentiaometrically using `Ce^(4+)` solution . Calculate the EMF of the oxidation electrode thus formed when
` 50%` of `Fe^(2+)` is titrated.
Fe2++Ce4+⇔Fe3++Ce3+

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AI Generated Solution

To calculate the EMF of the oxidation electrode when 50% of `Fe^(2+)` is titrated with `Ce^(4+)`, we can follow these steps: ### Step 1: Write the half-reaction for the oxidation of `Fe^(2+)` The oxidation reaction can be represented as follows: \[ \text{Fe}^{2+} \rightarrow \text{Fe}^{3+} + e^- \] ### Step 2: Set up the Nernst equation The Nernst equation for the half-cell reaction is given by: ...
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