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For the electrochemical cell, (M|M^(o+))...

For the electrochemical cell, `(M|M^(o+))||(X^(c-)|X)`, `E^(c-)._((M^(o+)|M))=0.44V`, and `E^(c-)._((X|X^(c-))=-0.33V`.
From this data, one can conclude that

A

`M+X rarr M^(o+)+X^(c-)` is a spontaneous reaction

B

`M^(o+)+X^(c-) rarr M+x` is the spontaneous reaction

C

`E^(c-)._(cell)=0.77V`

D

`E^(c-)._(cell)=-0.77V`

Text Solution

AI Generated Solution

The correct Answer is:
To analyze the electrochemical cell `(M|M^(o+))||(X^(c-)|X)` and draw conclusions based on the given standard reduction potentials, we can follow these steps: ### Step 1: Identify the Given Reduction Potentials We have the following standard reduction potentials: - For the half-reaction involving metal M: \[ E^\circ_{(M^{o+}/M)} = 0.44 \, \text{V} \] - For the half-reaction involving species X: \[ E^\circ_{(X/X^{c-})} = -0.33 \, \text{V} \] ### Step 2: Convert the Reduction Potential of M to Oxidation Potential The oxidation potential is the negative of the reduction potential. Therefore, the oxidation potential for the half-reaction of M is: \[ E^\circ_{(M/M^{o+})} = -E^\circ_{(M^{o+}/M)} = -0.44 \, \text{V} \] ### Step 3: Calculate the Standard Cell Potential (E°cell) To find the standard cell potential, we use the formula: \[ E^\circ_{cell} = E^\circ_{(cathode)} - E^\circ_{(anode)} \] In this case, X is the cathode (since it has a more positive reduction potential) and M is the anode. Thus: \[ E^\circ_{cell} = E^\circ_{(X/X^{c-})} - E^\circ_{(M/M^{o+})} \] Substituting the values: \[ E^\circ_{cell} = (-0.33 \, \text{V}) - (-0.44 \, \text{V}) = -0.33 + 0.44 = 0.11 \, \text{V} \] ### Step 4: Determine the Spontaneity of the Reaction A positive E°cell indicates that the reaction is spontaneous. Since we calculated: \[ E^\circ_{cell} = 0.11 \, \text{V} > 0 \] This means the reaction is spontaneous under standard conditions. ### Conclusion From the data provided, we can conclude that the electrochemical reaction in this cell is spontaneous because the standard cell potential (E°cell) is positive. ---

To analyze the electrochemical cell `(M|M^(o+))||(X^(c-)|X)` and draw conclusions based on the given standard reduction potentials, we can follow these steps: ### Step 1: Identify the Given Reduction Potentials We have the following standard reduction potentials: - For the half-reaction involving metal M: \[ E^\circ_{(M^{o+}/M)} = 0.44 \, \text{V} \] ...
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