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Identify the correct statements (s):...

Identify the correct statements `(s):`

A

`wedge_(m)` increases with increase in temperature.

B

`wedge_(m)` decreases with increase in concentration.

C

Specific conductance increase with increase in concentration.

D

Specific conductance decreases with increse in temperature.

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The correct Answer is:
To solve the question of identifying the correct statements regarding molar conductivity and specific conductance, let's analyze each statement step by step. ### Step-by-Step Solution: 1. **Understanding Molar Conductivity:** - Molar conductivity (Λm) is defined as the conductance of all the ions produced by one mole of an electrolyte in a fixed volume of solution. It can be expressed mathematically as: \[ \Lambda_m = \frac{1000 \cdot K}{C} \] where \( K \) is the specific conductance and \( C \) is the concentration. 2. **Statement 1: Molar conductivity increases with increase in temperature.** - As temperature increases, the mobility of ions increases due to reduced viscosity of the solvent. This leads to an increase in conductance. Therefore, this statement is **true**. 3. **Statement 2: Molar conductivity decreases with increase in concentration.** - Molar conductivity is inversely proportional to concentration. As the concentration of ions increases, the interactions between ions also increase, which can hinder their movement. Thus, this statement is **true**. 4. **Statement 3: Specific conductance increases with increase in concentration.** - Specific conductance (K) is the conductance of all ions present in a specific volume of solution. As concentration increases, the number of ions in the solution increases, leading to higher conductance. Therefore, this statement is **true**. 5. **Statement 4: Specific conductance decreases with increase in temperature.** - Specific conductance increases with an increase in temperature due to the increased mobility of ions. Therefore, this statement is **false**. ### Summary of Statements: - **Statement 1:** True - **Statement 2:** True - **Statement 3:** True - **Statement 4:** False ### Final Conclusion: The correct statements are 1, 2, and 3. Only statement 4 is incorrect.

To solve the question of identifying the correct statements regarding molar conductivity and specific conductance, let's analyze each statement step by step. ### Step-by-Step Solution: 1. **Understanding Molar Conductivity:** - Molar conductivity (Λm) is defined as the conductance of all the ions produced by one mole of an electrolyte in a fixed volume of solution. It can be expressed mathematically as: \[ \Lambda_m = \frac{1000 \cdot K}{C} ...
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