Home
Class 12
CHEMISTRY
Assertion (A): The mobility of Na^(o+) i...

Assertion `(A):` The mobility of `Na^(o+)` is lower than that of `K^(o+)` ion.
Reason `(R): ` The ionic mobility depends upon the effective radius of the ion.

A

If both `(A)` and `(R)` are correct, and `(R)` is the correct explanation of `(A)`.

B

If both `(A)` and `(R)` are correct, but `(R)` is not the correct explanation of `(A)`.

C

If `(A)` is correct, but `(R)` is incorrect.

D

If `(A)` is incorrect, `(R)` is correct.

Text Solution

AI Generated Solution

The correct Answer is:
To solve the question regarding the assertion and reason about the ionic mobility of Na⁺ and K⁺ ions, we can follow these steps: ### Step 1: Understand the Assertion The assertion states that the mobility of Na⁺ (sodium ion) is lower than that of K⁺ (potassium ion). ### Step 2: Understand Ionic Mobility Ionic mobility is defined as the ability of an ion to move through a medium, typically a solution, under the influence of an electric field. It is influenced by several factors, including the size of the ion. ### Step 3: Compare the Effective Radii The effective radius of an ion is a measure of its size. In general, the ionic mobility is inversely proportional to the effective radius of the ion. This means that ions with a larger effective radius will have lower mobility. ### Step 4: Analyze the Sizes of Na⁺ and K⁺ - Sodium ion (Na⁺) has a smaller effective radius compared to potassium ion (K⁺). - Therefore, K⁺ has a larger effective radius than Na⁺. ### Step 5: Conclude the Assertion Since K⁺ has a larger effective radius, it will have higher mobility compared to Na⁺. Thus, the assertion that the mobility of Na⁺ is lower than that of K⁺ is **correct**. ### Step 6: Understand the Reason The reason states that ionic mobility depends on the effective radius of the ion. This is also **correct** because, as mentioned, larger ions typically have lower mobility. ### Step 7: Conclusion Both the assertion and the reason are correct, and the reason provides a correct explanation for the assertion. Therefore, the answer to the question is that both the assertion and reason are true, and the reason is the correct explanation of the assertion. ### Final Answer Both assertion (A) and reason (R) are correct, and R is the correct explanation of A. ---

To solve the question regarding the assertion and reason about the ionic mobility of Na⁺ and K⁺ ions, we can follow these steps: ### Step 1: Understand the Assertion The assertion states that the mobility of Na⁺ (sodium ion) is lower than that of K⁺ (potassium ion). ### Step 2: Understand Ionic Mobility Ionic mobility is defined as the ability of an ion to move through a medium, typically a solution, under the influence of an electric field. It is influenced by several factors, including the size of the ion. ...
Promotional Banner

Topper's Solved these Questions

  • ELECTROCHEMISTRY

    CENGAGE CHEMISTRY ENGLISH|Exercise Exerciseinterger|8 Videos
  • ELECTROCHEMISTRY

    CENGAGE CHEMISTRY ENGLISH|Exercise Exercisefill In The Blanks|25 Videos
  • ELECTROCHEMISTRY

    CENGAGE CHEMISTRY ENGLISH|Exercise Exercises Ingle Correct|178 Videos
  • D AND F BLOCK ELEMENTS

    CENGAGE CHEMISTRY ENGLISH|Exercise Archives Subjective|29 Videos
  • GENERAL PRINCIPLES AND PROCESS OF ISOLATION OF ELEMENTS

    CENGAGE CHEMISTRY ENGLISH|Exercise Archives (Subjective)|14 Videos

Similar Questions

Explore conceptually related problems

The size of Na^(o+) ion is same as that of

Ionic mobility of Li^(+) is less than Na^(+) and K^(+) because

Assertion (A) The O-O bond length in H_(2)O_(2) is shorter than that in O_(2) . Reason (R ) H_(2)O_(2) is ionic compound.

Assertion (A) The O-O bond length in H_(2)O_(2) is shorter than that in O_(2) . Reason (R ) H_(2)O_(2) is ionic compound.

The ion which has the lowest ionic mobility is

Assertion: The pK_(a) of acetic acid is lower than that of phenol. Reason : carboxylate ion is more resonance sabilised.

Assertion (A): Enthalpy of graphite is lower than that of diamond. Reason (R ) : Entropy of graphite is lower than that of diamond.

Assertion:The pK_(a) of acetic acid is lower than that of phenol. Reason:Phenoxide ion is more resonance stablised.

Assertion: The first ionisation energy of aluminium is lower than that of magnesium. Reason: The ionic radius of aluminium is smaller than that of magnesium.

Assertion (A): IE_(1) of N is lower than O . Reason (R ) : Across a period Z_(eff) decrease.

CENGAGE CHEMISTRY ENGLISH-ELECTROCHEMISTRY-Exerciseassertion -Reasoning
  1. Assertion (A): For four half- cell reactions involving different numbe...

    Text Solution

    |

  2. Assertion (A): 1 Faraday of electricity deposits 1 g equivalent of Ag ...

    Text Solution

    |

  3. Assertion (A): The mobility of Na^(o+) is lower than that of K^(o+) io...

    Text Solution

    |

  4. Define Equivalent conductivity.

    Text Solution

    |

  5. Assertion (A): wedge(m(H^(o+))) and wedge(m(overset(c)(O)H)) ions are ...

    Text Solution

    |

  6. Assertion (A): Ionic conductivities increase with increase of temperat...

    Text Solution

    |

  7. Assertion (A: Cell constant is the EMF of a cell. Reason (R): Cell c...

    Text Solution

    |

  8. Assertion (A): At the end of electrolysis using Pt electrodes, an aque...

    Text Solution

    |

  9. Assertion (A): Cu liberates H(2)(g) from a dilute solution of HCl. R...

    Text Solution

    |

  10. Assertion(A): Na^(o+) ions are discharged in preference to H^(o+) ions...

    Text Solution

    |

  11. Assertion (A) : Cu gets readily corroded in acidic aqueous solution. ...

    Text Solution

    |

  12. Assertion (A) : Galvanized iron is protected from Rusting. Reason (...

    Text Solution

    |

  13. A Daniell cell : Zn|Zn^(2+)||Cu^(2+)|Cu with E(cell)=1.1V is given. ...

    Text Solution

    |

  14. Assertion (A): The electrolysis of NaCl solution gives H(2)(g) at cath...

    Text Solution

    |

  15. Assertion (A) : Fe is protected from corrosing by connecting Mg metal ...

    Text Solution

    |

  16. Assertion (A) : The Daniell cell becomes dead after sometimes. Reaso...

    Text Solution

    |

  17. Assertion (A): wedge^(@).(eq(CH(3)COOH)) cannote be determines experim...

    Text Solution

    |

  18. Assertion (A) : The presence of CO(2) in the air accelerates corrosio...

    Text Solution

    |

  19. Assertion (A) : (H(2)+O(2)) fuel cell gives a constant voltages throug...

    Text Solution

    |

  20. Assertion (A) : In a Daniell cell, if the concentration of Cu^(2+) an...

    Text Solution

    |