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Assertion (A): At the end of electrolysi...

Assertion `(A):` At the end of electrolysis using `Pt` electrodes, an aqueous solution of `CuSO_(4)` turns colourless.
Reason `(R): CuSO_(4)` changes to `Cu(OH)_(2)` during electrolysis.
(a)If both `(A)` and `(R)` are correct, and `(R)` is the correct explanation of `(A)`.
(b)If both `(A)` and `(R)` are correct, but `(R)` is not the correct explanation of `(A)`.
(c)If `(A)` is correct, but `(R)` is incorrect.
(d)If `(A)` is incorrect, `(R)` is correct.

A

If both `(A)` and `(R)` are correct, and `(R)` is the correct explanation of `(A)`.

B

If both `(A)` and `(R)` are correct, but `(R)` is not the correct explanation of `(A)`.

C

If `(A)` is correct, but `(R)` is incorrect.

D

If `(A)` is incorrect, `(R)` is correct.

Text Solution

AI Generated Solution

The correct Answer is:
To solve the question, we will analyze both the assertion and the reason provided. ### Step-by-Step Solution: 1. **Understanding the Assertion (A)**: - The assertion states that at the end of electrolysis using platinum electrodes, an aqueous solution of CuSO₄ turns colorless. - During electrolysis, copper ions (Cu²⁺) are reduced at the cathode, leading to the deposition of copper metal. This process removes copper ions from the solution, which contributes to the color change. 2. **Analyzing the Electrolysis Process**: - At the cathode, Cu²⁺ ions gain electrons and are reduced to solid copper (Cu): \[ \text{Cu}^{2+} + 2e^- \rightarrow \text{Cu (s)} \] - At the anode, OH⁻ ions are oxidized to produce oxygen gas and water: \[ 4\text{OH}^- \rightarrow 2\text{H}_2\text{O} + \text{O}_2 + 4e^- \] - The remaining solution will contain sulfate ions (SO₄²⁻) and any leftover H⁺ ions from water, which do not contribute to color. 3. **Conclusion about Assertion (A)**: - Since copper ions are being reduced and removed from the solution, the solution indeed turns colorless as the concentration of colored Cu²⁺ ions decreases. 4. **Understanding the Reason (R)**: - The reason states that CuSO₄ changes to Cu(OH)₂ during electrolysis. - This statement is incorrect because CuSO₄ does not convert to Cu(OH)₂ during the electrolysis process. Instead, Cu²⁺ ions are deposited as solid copper, and OH⁻ ions are involved in the oxidation reaction at the anode. 5. **Conclusion about Reason (R)**: - The reason provided is incorrect as there is no formation of Cu(OH)₂ during the electrolysis of CuSO₄. 6. **Final Evaluation**: - Since assertion (A) is correct and reason (R) is incorrect, the correct option is: - **(c) If (A) is correct, but (R) is incorrect.**

To solve the question, we will analyze both the assertion and the reason provided. ### Step-by-Step Solution: 1. **Understanding the Assertion (A)**: - The assertion states that at the end of electrolysis using platinum electrodes, an aqueous solution of CuSO₄ turns colorless. - During electrolysis, copper ions (Cu²⁺) are reduced at the cathode, leading to the deposition of copper metal. This process removes copper ions from the solution, which contributes to the color change. ...
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