Home
Class 12
CHEMISTRY
Conisder the following statement for a s...

Conisder the following statement for a second order reaction and score of each statement.
`2A rarr P`
`|{:(,,"Score"),(a.,[A]=([A_(0)])/(1+kt),3),(b.,"A plot of" 1//[A]^(2) "vs time will be straight line",2),(c.,"Half life is long when the concentration is low",1):}|`
Find the total score of the correct statements.

Text Solution

AI Generated Solution

The correct Answer is:
To solve the question regarding the second-order reaction \(2A \rightarrow P\) and evaluate the correctness of the given statements, we will analyze each statement one by one. ### Step 1: Analyze Statement (a) **Statement (a):** \([A] = \frac{[A_0]}{1 + kt}\) For a second-order reaction, the integrated rate law is given by: \[ \frac{1}{[A]} = \frac{1}{[A_0]} + kt \] This means that the expression for \([A]\) is not correctly stated in statement (a). Therefore, statement (a) is **incorrect**. **Score for (a): 3 (incorrect)** ### Step 2: Analyze Statement (b) **Statement (b):** "A plot of \( \frac{1}{[A]^2} \) vs time will be a straight line." For a second-order reaction, the correct plot is: \[ \frac{1}{[A]} \text{ vs } t \] This will yield a straight line. However, plotting \( \frac{1}{[A]^2} \) vs time does not yield a straight line. Therefore, statement (b) is **incorrect**. **Score for (b): 2 (incorrect)** ### Step 3: Analyze Statement (c) **Statement (c):** "Half-life is long when the concentration is low." For a second-order reaction, the half-life (\(t_{1/2}\)) is given by: \[ t_{1/2} = \frac{1}{k[A_0]} \] This indicates that the half-life is inversely proportional to the initial concentration \([A_0]\). Therefore, if the concentration is low, the half-life will be long. Hence, statement (c) is **correct**. **Score for (c): 1 (correct)** ### Step 4: Calculate Total Score Now, we sum the scores of the correct statements: - Score for (a): 3 (incorrect) - Score for (b): 2 (incorrect) - Score for (c): 1 (correct) Total score = 0 (since only statement (c) is correct). ### Final Answer The total score of the correct statements is **1**. ---

To solve the question regarding the second-order reaction \(2A \rightarrow P\) and evaluate the correctness of the given statements, we will analyze each statement one by one. ### Step 1: Analyze Statement (a) **Statement (a):** \([A] = \frac{[A_0]}{1 + kt}\) For a second-order reaction, the integrated rate law is given by: \[ \frac{1}{[A]} = \frac{1}{[A_0]} + kt ...
Promotional Banner

Topper's Solved these Questions

  • CHEMICAL KINETICS

    CENGAGE CHEMISTRY ENGLISH|Exercise Exercises Fill In The Blanks|37 Videos
  • CHEMICAL KINETICS

    CENGAGE CHEMISTRY ENGLISH|Exercise Exercises True/False|29 Videos
  • CHEMICAL KINETICS

    CENGAGE CHEMISTRY ENGLISH|Exercise Exercises Assertion-Reasoning|22 Videos
  • CARBOXYLIC ACIDS AND THEIR DERIVATIVES

    CENGAGE CHEMISTRY ENGLISH|Exercise Exercises Archives (Analytical And Descriptive)|34 Videos
  • COORDINATION COMPOUNDS

    CENGAGE CHEMISTRY ENGLISH|Exercise Archives Subjective|18 Videos

Similar Questions

Explore conceptually related problems

A graph plotted between log t_((1)/(2)) vs log concentration is a straight line. What is your conclusion? [Given : n = order of reaction]

In the reaction A to B , if the concentration of A is plotted against time, the curves obtained will be as shown in Fig. 1 and 2. Predict the order of the reactions.

Find the correct Statement :Statement-1 : The S.D. of 5 scores 1 2 3 4 5 is sqrt2 . Statement-2 : S.D. = sqrt"variance"

The half-life of 2 sample are 0.1 and 0.4 seconds. Their respctive concentration are 200 and 50 respectively. What is the order of the reaction

For the first order reaction given below select the set having correct statements 2N_(2)O_(5)(g) rarr 4NO_(2)(g) + O_(2)(g) (1) The concentration of the reactant decreases exponentially with time (2) the reaction proceeds to 99.6 % completion in eight half life duration (3) the half life of the reaction depends on the intial concentration of the reactant (4) the half life of the reaction decrease with increasing temperature

For a reaction R rarr P , half -life (t_(1//2)) is observed to be independent of the initial concentration of reactants. What is the order of reaction ?

Consider the following reaction A to P1, B to P2 , C to P3 , D to P4 , The order of the above reaction are a,b,c and d, respectively . The following graph is obtained when log [rate ] vs. log [conc.] are plotted : Among the following the correct sequence for the order of the reaction is :

For the chemical reaction A + 2B rarr C , the rate of reaction is increased by 2.82 times when the concentration of A is doubled and increased by 9 times when the concentration of B was tripled. What is the order with respect to B and A and total order ?

For the following question, choose the correct answer from the codes (a), (b), (c) and (d) defined as follows: Statement I is true, Statement II is also true; Statement II is the correct explanation of Statement I. Statement I is true, Statement II is also true; Statement II is not the correct explanation of Statement I. Statement I is true; Statement II is false Statement I is false; Statement II is true. Let a , b , c , p , q be the real numbers. Suppose alpha,beta are the roots of the equation x^2+2p x+q=0 and alpha,1/beta are the roots of the equation a x^2+2b x+c=0, where beta^2 !in {-1,0,1}dot Statement I (p^2-q)(b^2-a c)geq0 and Statement II b !in p a or c !in q adot