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The temperature coefficient of a reactio...

The temperature coefficient of a reaction is determined by comparing velocity constant at two temperatures differing by……………… .

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To determine the temperature coefficient of a reaction, we need to compare the velocity constants at two different temperatures. The steps to arrive at the answer are as follows: ### Step-by-Step Solution: 1. **Understanding Temperature Coefficient**: The temperature coefficient (often denoted as 'μ') is a measure of how the rate of a chemical reaction changes with temperature. It is defined as the ratio of the rate constants (or velocity constants) of the reaction at two different temperatures. 2. **Selecting Temperature Difference**: To determine the temperature coefficient, we typically compare the rate constants at two temperatures that differ by a specific amount. The standard practice is to use a temperature difference of **10 degrees Celsius**. 3. **Mathematical Representation**: The temperature coefficient can be mathematically expressed as: \[ μ = \frac{K_{T + 10}}{K_T} \] where \( K_{T + 10} \) is the rate constant at the higher temperature (T + 10°C) and \( K_T \) is the rate constant at the lower temperature (T). 4. **Example**: If we take an example where we have the rate constants at 25°C and 35°C, we can express this as: \[ μ = \frac{K_{35°C}}{K_{25°C}} \] This ratio represents the temperature coefficient since the two temperatures differ by 10 degrees Celsius. 5. **Conclusion**: Therefore, the temperature coefficient of a reaction is determined by comparing the velocity constants at two temperatures that differ by **10 degrees Celsius**. ### Final Answer: The temperature coefficient of a reaction is determined by comparing velocity constants at two temperatures differing by **10 degrees Celsius**. ---
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CENGAGE CHEMISTRY ENGLISH-CHEMICAL KINETICS-Exercises Fill In The Blanks
  1. The half-change time for a first order reaction is 20 min hence the ra...

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  2. For a first order reaction, t(1//2) = underset(k)ul(...........).

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  3. For a first order reaction, A rarr B, the rate = k xx…………. .

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  4. The unit of first order rate constant is ………….. .

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  5. The unit of first order rate constant when concentration is measured i...

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  6. ……………………… reaction obeys the expresison t(1//2) = 1//ka in chemical ki...

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  7. The half-life periof of a first order reaction is…………..of initial conc...

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  8. A first order reaction has t(1//2) = 6.93 min. The rate constant is………...

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  9. The rate first order reaction is 2.4 xx 10^(-3) mol L^(-1) s^(-1), whe...

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  10. The rate of a second order reaction is 6 xx 10^(-5) mol L^(-1) s^(-1),...

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  11. The temperature coefficient of a reaction is determined by comparing v...

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  12. The value of temperatuer coefficient is usually………………. .

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  13. The reactions having low activation energy are……………reactions.

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  14. fill up the following with suitable terms (i) Activation energy = Th...

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  15. Increases in temeprature increases the number of ……………..colliisons.

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  16. In a multi-step reaction, the rate is determined by conisdering the………...

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  17. Molecularity is always a whole…………… while the order of reaction may be...

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  18. All radioactive decompoistion reactions are…………..order reactions.

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  19. The order of reaction of the inverison of cane sugar is …………… while it...

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  20. The difference of energy between activated complex and that of the rea...

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