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1.216 gm of an organic compound was reac...

1.216 gm of an organic compound was reacted under Kjeldahl's method and the ammonia evolved was absorbed in 100 ml `NH_2SO_4`. The remaining acid solution was made up to 500 ml by the addition of water. Twenty millilitres of the dilute solution required 32 ml `(N)/(10)` caustic soda solution for complete neutralisation. Calculate the percentage of nitrogen in the compound.

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To calculate the percentage of nitrogen in the organic compound using the Kjeldahl's method, we will follow these steps: ### Step 1: Determine the total volume of NaOH required for neutralization From the problem, we know that 20 ml of the dilute sulfuric acid solution required 32 ml of \( \frac{N}{10} \) NaOH for complete neutralization. To find out how much NaOH is needed for the entire 500 ml of the acid solution, we can set up a proportion: \[ \text{Total NaOH required} = \left(\frac{32 \, \text{ml}}{20 \, \text{ml}}\right) \times 500 \, \text{ml} = 800 \, \text{ml} ...
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CENGAGE CHEMISTRY ENGLISH-PURIFICATION OF ORGANIC COMPOUNDS AND QUALITATIVE AND QUANTITATIVE ANALYSIS-SOLVED EXAMPLES
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