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The prussian blue colour obtained during...

The prussian blue colour obtained during the test of nitrogen by lassaigne's test is due to the formation of:

A

`Fe[Fe(CN)_6]_3`

B

`Fe_2[Fe(CN)_6]`

C

`Fe_3[Fe(CN__6]_4`

D

`Na_4[Fe(CN)_6]`

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To solve the question regarding the Prussian blue color obtained during the test of nitrogen by Lassaigne's test, we can break down the process step by step: ### Step-by-Step Solution: 1. **Understanding Lassaigne's Test**: - Lassaigne's test is a qualitative analysis method used to detect the presence of nitrogen in organic compounds. It involves fusing the organic compound with sodium metal to form sodium cyanide. **Hint**: Remember that Lassaigne's test is specifically for detecting nitrogen. 2. **Formation of Sodium Cyanide**: - When the organic compound is fused with sodium, sodium cyanide (NaCN) is formed if nitrogen is present in the compound. **Hint**: Think about the reaction between sodium and nitrogen-containing organic compounds. 3. **Boiling with Iron(II) Sulfate**: - The sodium cyanide solution is then boiled with iron(II) sulfate (FeSO₄). The iron(II) ions (Fe²⁺) present in the solution will react with the cyanide ions (CN⁻) from sodium cyanide. **Hint**: Focus on the interaction between iron(II) ions and cyanide ions. 4. **Formation of Hexacyanoferrate(II)**: - This reaction leads to the formation of sodium hexacyanoferrate(II) (Na₂[Fe(CN)₆]), which is a complex ion. **Hint**: Remember that this complex is crucial for the next steps. 5. **Acidification and Oxidation**: - The solution is then acidified with concentrated sulfuric acid (H₂SO₄). During this process, some of the Fe²⁺ ions are oxidized to Fe³⁺ ions. **Hint**: Consider the role of sulfuric acid in facilitating oxidation. 6. **Formation of Prussian Blue**: - The Fe³⁺ ions then react with the sodium hexacyanoferrate(II) to form a complex known as iron(III) hexacyanoferrate(II), commonly referred to as Prussian blue (Fe₄[Fe(CN)₆]₃). **Hint**: Identify the final complex that gives the characteristic blue color. 7. **Conclusion**: - The formation of the complex Fe₄[Fe(CN)₆]₃ is responsible for the Prussian blue color, confirming the presence of nitrogen in the original organic compound. **Hint**: Summarize the entire process to see how each step leads to the final result. ### Final Answer: The Prussian blue color obtained during the test of nitrogen by Lassaigne's test is due to the formation of iron(III) hexacyanoferrate(II), represented by the formula Fe₄[Fe(CN)₆]₃.

To solve the question regarding the Prussian blue color obtained during the test of nitrogen by Lassaigne's test, we can break down the process step by step: ### Step-by-Step Solution: 1. **Understanding Lassaigne's Test**: - Lassaigne's test is a qualitative analysis method used to detect the presence of nitrogen in organic compounds. It involves fusing the organic compound with sodium metal to form sodium cyanide. **Hint**: Remember that Lassaigne's test is specifically for detecting nitrogen. ...
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CENGAGE CHEMISTRY ENGLISH-PURIFICATION OF ORGANIC COMPOUNDS AND QUALITATIVE AND QUANTITATIVE ANALYSIS-Single Correct Answer Type
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  2. An organic compound contains C = 40% , O = 53.34 % and H = 6.60 % . Th...

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  3. A compound contains C=90% and H=10% Empirical formula of the compound ...

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  4. The empirical formula of a compound is CH2O and its vapour density is ...

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  5. The molecular mass of a compound having empirical formula C2H5O is 90....

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  6. A compound contains 38.8%C,16%H, and 45.2%N The formula of the compoun...

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  7. A compound containing 80% C and 20% H is likely to be: C6 H6 C2 H6...

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  8. An organic compound on analysis gave C=42.8%, H=7.2%, andN=50% volume ...

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  9. 0.14 gm of an acid required 12.5 ml of 0.1 N NaOH for complete neutura...

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  10. The empirical formula of a compound is CH2. One mole of this compound ...

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  11. Insulin contains 3.4% suplhur.The minimum molecular mass of insulin is...

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  12. 0.24 g of a volatile gas , upon vaporisation gives 45 mL vapour at NTP...

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  13. Liquid benzene C(6)H(6)) burns in oxygen according to the equation, 2...

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  14. A compound which does not give positive test for nitrogen is: urea ...

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  15. The catalyst used in Kjeldahl's method for the entimation of nitrogen ...

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  16. The concentration of C = 85.45%, and H = 14.44% is not obeyed by the f...

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  17. The prussian blue colour obtained during the test of nitrogen by lassa...

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  18. Which of the following sodium compound is/are formed when as organic c...

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  19. In which of the following compounds, nitrogen cannot be tested by Lass...

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  20. In dumas method for the estimation of nitrogen in an organic compound,...

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