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Predict the number of stereoisomers for ...

Predict the number of stereoisomers for `2,5` heptadiene.

A

4

B

3

C

2

D

5

Text Solution

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The correct Answer is:
To predict the number of stereoisomers for 2,5-heptadiene, we can follow these steps: ### Step 1: Understand the structure of 2,5-heptadiene 2,5-heptadiene indicates that there are 7 carbon atoms (hepta) and two double bonds (diene) located at the 2nd and 5th positions. ### Step 2: Draw the structure We can draw the structure of 2,5-heptadiene as follows: ``` H H H H H | | | | | H--C==C--C--C==C--C--C--H | | | | | H H H H H ``` This structure shows the two double bonds located at the 2nd and 5th carbon atoms. ### Step 3: Identify the possibility of stereoisomerism Stereoisomers arise due to the presence of double bonds, which can have cis (Z) and trans (E) configurations. ### Step 4: Count the double bonds In 2,5-heptadiene, we have two double bonds. Each double bond can potentially give rise to stereoisomers: - The double bond at position 2 can be either cis or trans. - The double bond at position 5 can also be either cis or trans. ### Step 5: Apply the formula for stereoisomers For compounds with multiple double bonds, the number of stereoisomers can be calculated using the formula: \[ \text{Number of stereoisomers} = 2^n \] where \( n \) is the number of double bonds that can exhibit geometrical isomerism. However, since we have two double bonds, we must consider the symmetry and the fact that the terminal groups are the same. ### Step 6: Calculate the number of stereoisomers Using the formula for geometrical isomerism: \[ \text{Number of geometrical isomers} = 2^{n-1} + 2^{n-2} \] where \( n \) is the number of double bonds. For 2,5-heptadiene: - \( n = 2 \) (two double bonds) Substituting into the formula: \[ \text{Number of stereoisomers} = 2^{2-1} + 2^{2-2} = 2^1 + 2^0 = 2 + 1 = 3 \] ### Conclusion Thus, the total number of stereoisomers for 2,5-heptadiene is 3.

To predict the number of stereoisomers for 2,5-heptadiene, we can follow these steps: ### Step 1: Understand the structure of 2,5-heptadiene 2,5-heptadiene indicates that there are 7 carbon atoms (hepta) and two double bonds (diene) located at the 2nd and 5th positions. ### Step 2: Draw the structure We can draw the structure of 2,5-heptadiene as follows: ``` ...
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CENGAGE CHEMISTRY ENGLISH-ISOMERISM-Single correct answer type (Exercise)
  1. Predict the number of stereoisomers in CH(2)OH.(CHOH)(4).CHO.

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  2. Predict the number of stereoisomers for 2,5 heptadiene.

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  3. Symbol D stands for:

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  4. Which of the following compounds will not show geometrical isomerism?

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  5. The enolic form of acetone contains:

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  6. Arrange the following in the increasing order of expected enol content...

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  7. The decreasing order of reactivity of the following alkenes is: i. 2...

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  8. Which of the following is the least stable form of cyclohexane?

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  9. The minimum number of carbon atoms an alkane should contain in order t...

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  10. A compound whose molecule is superimposabel on its mirror image despit...

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  11. The IUPAC name of the compound with formula C(n)H(2n+2), having the lo...

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  12. A racemic mixtrue is optically inactive due to :

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  13. The pair of structures given below represents:

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  14. The degree of unsaturation or index of hydrogen deficiency in the foll...

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  15. The degree of unsaturation in i. C(3)H(3)Cl(3), ii. C(3)H(4)O, iii. ...

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  16. Which of the following alkenes is most stable?

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  17. Which of the following will have zero dipole moment?

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  18. The number of conformations exhibited by ethane is

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  19. Which of the following is not an isomer of butanal?

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  20. The least energetic conformation of cyclohexane is:

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