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Symbol D stands for:...

Symbol `D` stands for:

A

(a) Dextrorotatory, which rotates `P.P.L.` towards right.

B

(b) Dextrorotatory, which rotates `P.P.L`. towards left.

C

(c) Relative configuration with respect to lactic acid taken as standard.

D

(d) Relative configuration with respect to glyceraldehyde taken as standard and `(OH)` group is on the right side.

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The correct Answer is:
To determine what the symbol `D` stands for in the context of isomerism, particularly in organic chemistry, we can follow these steps: ### Step-by-Step Solution: 1. **Understanding Optical Activity**: - Optical activity refers to the ability of a compound to rotate plane-polarized light. Compounds can be classified as dextrorotatory (rotating light to the right) or levorotatory (rotating light to the left). - The symbols used for these classifications are small `d` for dextrorotatory and small `l` for levorotatory. **Hint**: Recall that dextrorotatory compounds are those that rotate light to the right, while levorotatory compounds rotate it to the left. 2. **Identifying Capital D and L**: - The capital letters `D` and `L` do not refer to optical activity but rather to the relative configuration of certain sugars and amino acids. - The designation of `D` or `L` is based on the configuration of the molecule in relation to the reference compound glyceraldehyde. **Hint**: Remember that `D` and `L` are related to the configuration of molecules and not their optical activity. 3. **Reference Compound**: - Glyceraldehyde is the reference compound used to determine whether a sugar or amino acid is classified as `D` or `L`. - If the hydroxyl group (OH) on the penultimate carbon (the second to last carbon) of the molecule is on the right side in a Fischer projection, the compound is designated as `D`. If it is on the left side, it is designated as `L`. **Hint**: Visualize the Fischer projection of glyceraldehyde to understand the positioning of the hydroxyl group. 4. **Conclusion**: - Therefore, the symbol `D` stands for the relative configuration of a molecule with respect to glyceraldehyde, specifically indicating that the hydroxyl group is on the right side. **Hint**: Think of `D` as indicating the right-hand position of the hydroxyl group in the Fischer projection of glyceraldehyde. ### Final Answer: The symbol `D` stands for relative configuration with respect to glyceraldehyde, where the hydroxyl group is on the right side.
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