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The minimum number of carbon atoms an al...

The minimum number of carbon atoms an alkane should contain in order to exhibit optical activity is:

A

5

B

6

C

7

D

8

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The correct Answer is:
To determine the minimum number of carbon atoms an alkane should contain in order to exhibit optical activity, we need to understand the concept of chirality and asymmetric carbon atoms. ### Step-by-Step Solution: 1. **Understanding Optical Activity**: - Optical activity in organic compounds arises when a molecule has a chiral center, which is typically a carbon atom bonded to four different groups. This carbon atom is referred to as an asymmetric carbon. 2. **Identifying Asymmetric Carbon**: - For a carbon atom to be asymmetric, it must be bonded to four different substituents. This means that if we want to create an optically active alkane, we need to ensure that at least one of the carbon atoms in the molecule has four distinct groups attached. 3. **Constructing an Alkane**: - Let's consider the simplest alkane structure that can potentially have an asymmetric carbon. Starting with a straight-chain alkane, we can analyze the structure of alkanes with increasing carbon counts. 4. **Minimum Carbon Count**: - For an alkane to have an asymmetric carbon, we can start with a 7-carbon alkane (heptane). - In heptane, we can create a branched structure (for example, 2-methylhexane) where one of the carbon atoms is bonded to four different groups: - One hydrogen atom - One methyl group (−CH3) - One ethyl group (−C2H5) - One propyl group (−C3H7) 5. **Counting the Carbons**: - In the branched structure, we have: - 1 carbon from the methyl group - 2 carbons from the ethyl group - 3 carbons from the propyl group - 1 carbon from the asymmetric carbon itself - This gives us a total of 7 carbon atoms. 6. **Conclusion**: - Therefore, the minimum number of carbon atoms an alkane should contain in order to exhibit optical activity is **7**. ### Final Answer: The minimum number of carbon atoms an alkane should contain in order to exhibit optical activity is **7**.

To determine the minimum number of carbon atoms an alkane should contain in order to exhibit optical activity, we need to understand the concept of chirality and asymmetric carbon atoms. ### Step-by-Step Solution: 1. **Understanding Optical Activity**: - Optical activity in organic compounds arises when a molecule has a chiral center, which is typically a carbon atom bonded to four different groups. This carbon atom is referred to as an asymmetric carbon. 2. **Identifying Asymmetric Carbon**: ...
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CENGAGE CHEMISTRY ENGLISH-ISOMERISM-Single correct answer type (Exercise)
  1. The decreasing order of reactivity of the following alkenes is: i. 2...

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  2. Which of the following is the least stable form of cyclohexane?

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  3. The minimum number of carbon atoms an alkane should contain in order t...

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  4. A compound whose molecule is superimposabel on its mirror image despit...

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  5. The IUPAC name of the compound with formula C(n)H(2n+2), having the lo...

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  6. A racemic mixtrue is optically inactive due to :

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  7. The pair of structures given below represents:

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  8. The degree of unsaturation or index of hydrogen deficiency in the foll...

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  9. The degree of unsaturation in i. C(3)H(3)Cl(3), ii. C(3)H(4)O, iii. ...

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  10. Which of the following alkenes is most stable?

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  11. Which of the following will have zero dipole moment?

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  12. The number of conformations exhibited by ethane is

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  13. Which of the following is not an isomer of butanal?

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  14. The least energetic conformation of cyclohexane is:

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  15. How many chiral carbons are present in glucose molecule CHO(CHOH)(4)CH...

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  16. The process of separation of a recemic mixture into d- and 1- componen...

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  17. If a compound has n asymmetric carbon atoms with different terminal gr...

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  18. How many chiral compounds are possible on monochlorination of 2-methyl...

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  19. A hydrocarbon with formula C(8)H(18) gives one monochloro derivative. ...

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  20. The most stained cycloalkane is :

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