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The smallest aldehyde and its next homol...

The smallest aldehyde and its next homologue are treated with `NH_(2)OH` to form oxime. Find out the correct answer out of the following.

A

Two different oximes are formed

B

Three different oximes are formed.

C

Two oximes are optically active.

D

All oximes are optically active.

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The correct Answer is:
To solve the problem, we need to identify the smallest aldehyde and its next homologue, treat them with hydroxylamine (NH₂OH) to form oximes, and analyze the properties of the resulting oximes. ### Step-by-Step Solution: 1. **Identify the Smallest Aldehyde:** - The smallest aldehyde is formaldehyde, which has the chemical formula HCHO. 2. **Identify the Next Homologue:** - The next homologue of formaldehyde is acetaldehyde, which has the chemical formula CH₃CHO. 3. **React with Hydroxylamine:** - When formaldehyde (HCHO) reacts with hydroxylamine (NH₂OH), it forms an oxime. The reaction can be represented as: \[ \text{HCHO} + \text{NH}_2\text{OH} \rightarrow \text{C}=\text{N-OH} + \text{H}_2\text{O} \] - The oxime formed from formaldehyde is hydroxymethyl oxime (H₂C=NOH). 4. **Draw the Structure of the Oxime:** - The structure of the oxime formed from formaldehyde is: \[ \text{H}_2C=NOH \] 5. **React Acetaldehyde with Hydroxylamine:** - When acetaldehyde (CH₃CHO) reacts with hydroxylamine, it also forms an oxime: \[ \text{CH}_3\text{CHO} + \text{NH}_2\text{OH} \rightarrow \text{C}(\text{CH}_3)=\text{N-OH} + \text{H}_2\text{O} \] - The oxime formed from acetaldehyde is CH₃C(=NOH)H. 6. **Draw the Structure of the Oxime:** - The structure of the oxime formed from acetaldehyde can be represented as: \[ \text{CH}_3C=NOH \] 7. **Analyze the Oximes for Chirality:** - The oxime from formaldehyde (H₂C=NOH) is not chiral because it has two identical hydrogen atoms attached to the carbon. - The oxime from acetaldehyde (CH₃C=NOH) can exist in two configurations: E and Z. - The Z configuration has the CH₃ and OH groups on the same side, making it chiral and optically active. - The E configuration has the CH₃ and OH groups on opposite sides, making it achiral and optically inactive. 8. **Count the Different Oximes:** - From the above analysis, we have: - One oxime from formaldehyde (not optically active). - Two forms (E and Z) from acetaldehyde (one of which is optically active). - Therefore, we have a total of three different oximes. 9. **Conclusion:** - The correct answer is that there are three different oximes formed, and only one of them is optically active. ### Final Answer: The correct option is **three different oximes, with one being optically active.**

To solve the problem, we need to identify the smallest aldehyde and its next homologue, treat them with hydroxylamine (NH₂OH) to form oximes, and analyze the properties of the resulting oximes. ### Step-by-Step Solution: 1. **Identify the Smallest Aldehyde:** - The smallest aldehyde is formaldehyde, which has the chemical formula HCHO. 2. **Identify the Next Homologue:** ...
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CENGAGE CHEMISTRY ENGLISH-ISOMERISM-Single correct answer type (Exercise)
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  2. The geometrical isomerism is shown by:

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  4. The smallest aldehyde and its next homologue are treated with NH(2)OH ...

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  5. What are the numerical values of N and M?

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  6. Molecule in which the distance between two adjacent carbon atom is lar...

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  7. The compound which is not isomeric with diethyl ether is:

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  8. Among the following, the compound that can be most readily sulphonated...

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  9. Which of the following compounds will exhibit cis-trans (geometrical) ...

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  10. An isomer of ethanol is:

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  11. Which of the following will have the least hindered rotation about car...

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  12. The number of isomers of C(6)H(14) is:

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  13. The enolic form of acetone contains:

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  14. Three dimensional arrangements which ca be interconverted into one ano...

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  15. How many optically active stereoisomers are possible for butane-2, 3-d...

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  16. The optically active tartaric acid is named as D-(+)- tartaric acid be...

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  17. Which of the following compounds will exhibit geometrical isomerism ?

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  18. The number of isomers of the compound C(2)FClBrl is :

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  19. Which of the following compounds exhibits stereoisomerism?

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  20. In the above compound, C(2) is rotated clockwise 120^(@) about C(2)-C(...

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