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Assertion (A): The cis form of (CH(3)...

Assertion (A): The cis form of
`(CH_(3)-underset(Cl)underset(|)(CH)-CH=CH-underset(Cl)underset(|)(CH)-CH_(3))`
exist in three-diastereomers.
Reason (R ): One form is optically inactive due to the presence of centre of symmetry.

A

If both (A) and (R ) are true and (R ) is the correct explanation for (A).

B

If both (A) and (R ) are true and (R ) is not the true explanation for (A)

C

If (A) is true, but (R ) is false.

D

If both (A) and (R ) are false

Text Solution

AI Generated Solution

The correct Answer is:
To solve the question, we need to analyze the assertion and reason provided. ### Step 1: Understanding the Assertion The assertion states that the cis form of the compound `(CH₃-Cl-CH=CH-Cl-CH₃)` exists in three diastereomers. 1. **Identify the structure**: The compound has a double bond between two carbon atoms, and each of these carbon atoms is attached to different groups (Cl, CH₃, and H). 2. **Cis form**: The cis form means that the two Cl atoms are on the same side of the double bond. 3. **Chirality**: Each of the two carbons involved in the double bond is chiral because they are attached to four different groups. ### Step 2: Counting Diastereomers To determine the number of diastereomers: 1. **Chiral centers**: There are two chiral centers in the compound. 2. **Formula for diastereomers**: The number of diastereomers can be calculated using the formula \(2^n\), where \(n\) is the number of chiral centers. However, we need to account for the fact that some of these may be meso compounds (optically inactive). 3. **Meso compounds**: In this case, the presence of a plane of symmetry in one of the configurations leads to the formation of a meso compound. ### Step 3: Conclusion on Assertion - **Total diastereomers**: After considering the chiral centers and meso form, we find that the total number of diastereomers is indeed three (2 optical isomers + 1 meso compound). - Therefore, the assertion is **true**. ### Step 4: Understanding the Reason The reason states that one form is optically inactive due to the presence of a center of symmetry. 1. **Optical inactivity**: The meso form is optically inactive due to its symmetry. However, it is important to note that this is due to a **plane of symmetry**, not a center of symmetry. 2. **Center of symmetry**: A center of symmetry is a point in the molecule where for every atom, there is an equivalent atom at an equal distance on the opposite side. In this case, the compound does not have a center of symmetry. ### Step 5: Conclusion on Reason - Since the reason incorrectly attributes the optical inactivity to a center of symmetry instead of a plane of symmetry, the reason is **false**. ### Final Conclusion - The assertion is true, and the reason is false. Therefore, the correct answer is that the assertion is true, and the reason is false.

To solve the question, we need to analyze the assertion and reason provided. ### Step 1: Understanding the Assertion The assertion states that the cis form of the compound `(CH₃-Cl-CH=CH-Cl-CH₃)` exists in three diastereomers. 1. **Identify the structure**: The compound has a double bond between two carbon atoms, and each of these carbon atoms is attached to different groups (Cl, CH₃, and H). 2. **Cis form**: The cis form means that the two Cl atoms are on the same side of the double bond. 3. **Chirality**: Each of the two carbons involved in the double bond is chiral because they are attached to four different groups. ...
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