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The I(3)^(Θ) ion has ....

The `I_(3)^(Θ)` ion has .

A

Five equatorial lone pairs on the central I atom and two axial bonding pairs in a trigonal bipyramidal arrangement.

B

Five equatorial lone pairs on the central I atom and two axial bonding pairs in a pentagonal bipyramidal arrangement

C

Three equatorial lone pairs on the central I atom and two axial bonding pairs in a trigonal bipyramidal arrangement .

D

Two equatorial lone pairs on the central I atom and three axial bonding pairs in a trigonal bipyramidal arrangement .

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To determine the geometry and shape of the \( I_3^- \) ion using VSEPR theory, we can follow these steps: ### Step 1: Identify the central atom and count the valence electrons The central atom in the \( I_3^- \) ion is iodine (I). Iodine is in group 17 of the periodic table and has 7 valence electrons. Since there are three iodine atoms in the ion and it carries a negative charge, we need to account for the additional electron from the charge. - Total valence electrons = \( 3 \times 7 + 1 = 22 \) electrons. ### Step 2: Determine the number of bonding pairs and lone pairs In the \( I_3^- \) ion, there are two iodine atoms bonded to the central iodine atom. This means there are 2 bonding pairs. The remaining electrons will be lone pairs. - Total electrons used in bonding = 2 (for the two I-I bonds). - Remaining electrons = \( 22 - 4 = 18 \) electrons. - Lone pairs = \( \frac{18}{2} = 9 \) lone pairs. ### Step 3: Arrange the electron pairs According to VSEPR theory, we need to arrange the electron pairs around the central atom to minimize repulsion. - The total number of electron pairs (bonding + lone pairs) is \( 2 \) (bonding pairs) + \( 3 \) (lone pairs) = \( 5 \) electron pairs. ### Step 4: Determine the hybridization With 5 electron pairs, the hybridization can be determined as follows: - Hybridization = \( sp^3d \). ### Step 5: Identify the geometry The arrangement of 5 electron pairs corresponds to a trigonal bipyramidal geometry. ### Step 6: Determine the molecular shape In the case of \( I_3^- \), the three lone pairs will occupy the equatorial positions to minimize repulsion, while the two iodine atoms will occupy the axial positions. - Therefore, the molecular shape is linear. ### Conclusion The \( I_3^- \) ion has a trigonal bipyramidal electron geometry with a linear molecular shape. ### Summary of the solution: 1. Central atom: Iodine (I). 2. Total valence electrons: 22. 3. Bonding pairs: 2, Lone pairs: 3. 4. Hybridization: \( sp^3d \). 5. Geometry: Trigonal bipyramidal. 6. Molecular shape: Linear.

To determine the geometry and shape of the \( I_3^- \) ion using VSEPR theory, we can follow these steps: ### Step 1: Identify the central atom and count the valence electrons The central atom in the \( I_3^- \) ion is iodine (I). Iodine is in group 17 of the periodic table and has 7 valence electrons. Since there are three iodine atoms in the ion and it carries a negative charge, we need to account for the additional electron from the charge. - Total valence electrons = \( 3 \times 7 + 1 = 22 \) electrons. ### Step 2: Determine the number of bonding pairs and lone pairs ...
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CENGAGE CHEMISTRY ENGLISH-CHEMICAL BONDING AND MOLECULAR STRUCTURE-Exercises Single Correct (Hybridisation)
  1. The shapes of PCI(4)^(o+),PCI(4)^(Θ) and AsCI(5) and are respectively...

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  2. The I(3)^(Θ) ion has .

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  3. In the reaction 2PCI(5) hArr PCI(4)^(o+) + PCI(6)^(Θ) change in hybrid...

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  4. There are four species CO(2),N(3) Θ,NO(2)^(o+) and I(3)^(Θ) Which of t...

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  5. On hybridization of one s and one p orbital we get

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  6. Which moleucle is T-shaped ?

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  7. The hybridisation of the central atom in ICI(2)^(o+) is .

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  8. The molecule that has linear structure is

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  9. The species which has pyramidal shape is

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  10. The compounds in which C uses its sp^(3)- hybrid orbitals for bond for...

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  11. Which one of the following compounds has sp^(2) hybridisation ? .

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  12. CO(2) has same geometry as

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  13. In which pair of species both species do have the similar geometry ? .

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  14. The geometry and the type of hybrid orbitals present about the central...

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  15. SF(2),SF(4) and SF(6) have the hybridisation at sulphur atom respectiv...

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  16. Two types FXF angles are presnet in which of the following molecule (X...

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  17. A sigma bonded molecule MX(3) is T-shaped The number of non-bonding pa...

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  18. In NH(4)^+ and OF(2) th hybridisation of central atom respectively are...

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  19. Hybridisation involves .

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  20. As PF(5) molecule is sp^(3) d hybridised and is trigonal bipyramidal (...

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