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The linear struture is assumed by :...

The linear struture is assumed by :

A

`SnCI_(2)`

B

`CS_(2)`

C

`NO_(2)^(o+)`

D

`NCO^(Theta)`

Text Solution

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The correct Answer is:
To determine which of the compounds has a linear structure, we will analyze each compound one by one based on their molecular geometry. ### Step-by-Step Solution: 1. **Understanding Linear Structure**: - A linear structure occurs when the atoms are arranged in a straight line, resulting in a bond angle of 180 degrees. This typically happens in molecules with the general formula AB2, where A is the central atom and B represents the surrounding atoms. 2. **Analyzing SnCl2**: - **Lewis Structure**: SnCl2 has a central tin (Sn) atom bonded to two chlorine (Cl) atoms. - **Lone Pairs**: Tin has one lone pair of electrons. - **Molecular Geometry**: The presence of the lone pair distorts the bond angle from 180 degrees to about 95 degrees, resulting in a bent structure rather than a linear one. - **Conclusion**: SnCl2 does not have a linear structure. 3. **Analyzing CS2**: - **Lewis Structure**: CS2 consists of a central carbon (C) atom bonded to two sulfur (S) atoms. - **Molecular Geometry**: There are no lone pairs on the carbon atom, and the bond angle is 180 degrees. - **Conclusion**: CS2 has a linear structure. 4. **Analyzing NO2+ (Nitronium Ion)**: - **Lewis Structure**: NO2+ has a nitrogen (N) atom bonded to two oxygen (O) atoms. - **Molecular Geometry**: The ion is isoelectronic with CS2, and the structure is linear with a bond angle of 180 degrees. - **Conclusion**: NO2+ has a linear structure. 5. **Analyzing NCO- (Cyanate Ion)**: - **Lewis Structure**: NCO- has a nitrogen (N) atom bonded to a carbon (C) atom, which is then bonded to an oxygen (O) atom. - **Molecular Geometry**: The presence of the negative charge does not affect the linear arrangement, and it maintains a bond angle of 180 degrees. - **Conclusion**: NCO- has a linear structure. ### Final Conclusion: The compounds that exhibit a linear structure are: - CS2 - NO2+ - NCO-

To determine which of the compounds has a linear structure, we will analyze each compound one by one based on their molecular geometry. ### Step-by-Step Solution: 1. **Understanding Linear Structure**: - A linear structure occurs when the atoms are arranged in a straight line, resulting in a bond angle of 180 degrees. This typically happens in molecules with the general formula AB2, where A is the central atom and B represents the surrounding atoms. 2. **Analyzing SnCl2**: ...
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