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20mL of H2O2 is reacted completely with ...

`20mL` of `H_2O_2` is reacted completely with acidified `K_2Cr_2O_7` solution. `40mL` of `K_2Cr_2O_7` solution is required to oxidise the `H_2O_2` completely. Also, `2.0mL` of the same `K_2Cr_2O_7` solution is required to oxidise `5.0mL` of a `1.0MH_2C_2O_4` solution to reach equivalence point. Which of the following statements is`//`are correct?

A

The `H_(2)O_(2)` solution is `5M`

B

The volume strength of `H_(2)O_(2)` is `56 V`

C

The volume strength of `H_(2)O_(2)` is `112 V`

D

If `40 mL` more `5M//8H_(2)O` is further added to the `10 mL` of the above `H_(2)O_(2)` solution, the volume strength of the resulting solution is changed to `16.8 V`

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To solve the problem step-by-step, we will analyze the information given and apply stoichiometry principles. ### Step 1: Determine the n-factor for each reactant 1. **For K2Cr2O7 (Potassium dichromate)**: - The reduction half-reaction is: \[ Cr_2O_7^{2-} + 6e^- \rightarrow 2Cr^{3+} \] - The n-factor is 6. 2. **For H2O2 (Hydrogen peroxide)**: - The oxidation half-reaction is: \[ H_2O_2 + 2H^+ + 2e^- \rightarrow 2H_2O \] - The n-factor is 2. 3. **For H2C2O4 (Oxalic acid)**: - The oxidation half-reaction is: \[ C_2O_4^{2-} \rightarrow 2CO_2 + 2e^- \] - The n-factor is also 2. ### Step 2: Calculate the concentration of K2Cr2O7 - Given that 40 mL of K2Cr2O7 is required to oxidize 20 mL of H2O2: \[ \text{Milliequivalents of } K_2Cr_2O_7 = n \times C \times V \] - For K2Cr2O7: \[ \text{Milliequivalents} = 6 \times C_{K_2Cr_2O_7} \times 40 \text{ mL} \] - For H2O2: \[ \text{Milliequivalents} = 2 \times C_{H_2O_2} \times 20 \text{ mL} \] - Setting them equal gives: \[ 6 \times C_{K_2Cr_2O_7} \times 40 = 2 \times C_{H_2O_2} \times 20 \] ### Step 3: Solve for the concentration of K2Cr2O7 - Rearranging the equation: \[ C_{K_2Cr_2O_7} = \frac{2 \times C_{H_2O_2} \times 20}{6 \times 40} \] - Simplifying: \[ C_{K_2Cr_2O_7} = \frac{C_{H_2O_2}}{12} \] ### Step 4: Calculate the concentration of H2C2O4 - Given that 2 mL of K2Cr2O7 is required to oxidize 5 mL of 1.0 M H2C2O4: \[ \text{Milliequivalents of } K_2Cr_2O_7 = 6 \times C_{K_2Cr_2O_7} \times 2 \] \[ \text{Milliequivalents of } H_2C_2O_4 = 2 \times 1.0 \times 5 \] - Setting them equal gives: \[ 6 \times C_{K_2Cr_2O_7} \times 2 = 2 \times 1.0 \times 5 \] - Solving for \( C_{K_2Cr_2O_7} \): \[ C_{K_2Cr_2O_7} = \frac{5}{6} \] ### Step 5: Substitute back to find the concentration of H2O2 - From Step 3: \[ C_{K_2Cr_2O_7} = \frac{C_{H_2O_2}}{12} \] - Substituting \( C_{K_2Cr_2O_7} = \frac{5}{6} \): \[ \frac{5}{6} = \frac{C_{H_2O_2}}{12} \] - Solving for \( C_{H_2O_2} \): \[ C_{H_2O_2} = \frac{5 \times 12}{6} = 10 \text{ M} \] ### Step 6: Calculate the volume strength of H2O2 - The volume strength is calculated as: \[ \text{Volume strength} = 11.2 \times C_{H_2O_2} \] - Thus: \[ \text{Volume strength} = 11.2 \times 10 = 112 \text{ volume} \] ### Conclusion - The correct statements based on the calculations are: - A: Correct - B: Correct - D: Correct - C: Incorrect

To solve the problem step-by-step, we will analyze the information given and apply stoichiometry principles. ### Step 1: Determine the n-factor for each reactant 1. **For K2Cr2O7 (Potassium dichromate)**: - The reduction half-reaction is: \[ Cr_2O_7^{2-} + 6e^- \rightarrow 2Cr^{3+} \] ...
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