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The electrolyte, used in Castner's proce...

The electrolyte, used in Castner's proceed of sodium extraction is

A

anhydrous `Na_(2)CO_(3)`

B

aqueous NaOH

C

`NaCI+CaCI_(2)`

D

fused anhdrous NaOH

Text Solution

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The correct Answer is:
To solve the question regarding the electrolyte used in Castner's process of sodium extraction, we can follow these steps: ### Step-by-Step Solution: 1. **Understanding the Castner Process**: The Castner process is a method for extracting sodium metal through electrolysis. It involves the electrolysis of a specific electrolyte. 2. **Identifying the Electrolyte**: The electrolyte used in the Castner process is fused sodium hydroxide (NaOH). This means that sodium hydroxide is heated until it becomes a liquid, allowing the ions to move freely. 3. **Electrolysis Reaction**: During the electrolysis of fused NaOH: - At the **cathode**, sodium ions (Na⁺) gain electrons (reduction) to form sodium metal (Na). - At the **anode**, hydroxide ions (OH⁻) lose electrons (oxidation) to produce water (H₂O) and oxygen gas (O₂). 4. **Final Confirmation**: The correct electrolyte for the Castner process is indeed fused anhydrous sodium hydroxide (NaOH), as it allows for the necessary ionic movement for the electrolysis to occur effectively. ### Conclusion: The electrolyte used in Castner's process of sodium extraction is **fused anhydrous NaOH**. ---
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