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KO(2) find use in breathing equipment an...

`KO_(2)` find use in breathing equipment and safeguards the user to breathe in oxygen generated internally in the apparatus without
being exposed to toxic fumes ouside. The supply of oxygen is due
to

A

Slow decomposition of `KO_(2)`

B

Reaction of `KO_(2)` with `CO_(2)` in the exhaled air

C

Reaction of `KO_(2)` with moisture in the essential air

D

Fast decomposition of `KO_(2)`

Text Solution

Verified by Experts

The correct Answer is:
B, C

`2KO_(2)+CO_(2)rarr K_(2)CO_(3)+(3)/(2)O_(2)`
`2KO_(2)+2H_(2)O rarr 2KOH+H_(2)O_(2)+O_(2)`
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Alkali metals oxide are obtained by combustion of the metals.Although Na normally gives Na_2O_2 ,it will take up further oxygen at elevated pressure and temperature to form NaO_2 .The per and superoxides of the heavier alkalies can also be prepared by passing stoichiometric amounts of oxygen into their solution in liquid ammonia. The different alkali metal oxides can be distinguished by reaction with water.The superoxides reacts with CO_2 and give oxygen gas.The stability of per and superoxides is based upon that larger cation can stablise larger anion, due to larger lattice energy. Alkali metals dissolve in liquid ammonia.Dilute solutions are dark blue in colour but as the concentration increases above 3M, the colour changes to copper bronze and the solution acquires the metallic lusture due to the formation of metal ions clusters.The solutions of alkali metals in liquid ammonia are good conductors of electricity due to the presence of ammoniated cations and ammoniated electrons.However, the conductivity decreases as the concentrations increases, since ammoniated electrons and ammoniated cation associate. KO_2 is used in oxygen cylinders in space and submarines because it :

CENGAGE CHEMISTRY ENGLISH-S-BLOCK GROUP 1 - ALKALI METALS-Exercises Multiple Correct
  1. Camallites is an ore of

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  2. Which of the following compound is/are efforescent ?

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  3. KO(2) find use in breathing equipment and safeguards the user to breat...

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  4. During electrolysis of aqueous solution of NaCI in Castner Kellner cel...

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  5. Which of the following reaction (s) correct ?

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  6. When a mixture of Li(2)CO(3) and Na(2)CO(3). 10H(2)O is heated strongl...

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  7. The pair of compounds which cannot exist together in aqueous solution ...

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  8. Alkali metlas are characterised by

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  9. Select wrong statements about alkali metals:

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  10. A highly pure dilute solution of sodium in liquid ammonia:

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  11. Li has the following abnormal behaviour in its group:

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  12. Which among the following compounds is paramagnetic ?

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  13. Nitrate of which of the following elements are converted to their oxid...

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  14. The compounds(s) formed upon combustion of sodium metal excess air is...

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  15. An alloy of Na and K is

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  16. Which of the following is/are correct ?

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  17. Sodium chloride is known as

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  18. The compounds) used in Solvay process is/are

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  19. What is atomic number of sodium and Why is sodium metal kept under ker...

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  20. Which of the following carbonates does not evolve CO(2) on heating?

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