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The products of electrolysis of concentr...

The products of electrolysis of concentrated common salt solution are

A

`Na+CI_(2)`

B

`H_(2)+O_(2)`

C

`NaOH+H_(2)+CI_(2)`

D

`NaOH+CI_(2)+O_(2)`

Text Solution

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To determine the products of the electrolysis of concentrated common salt solution (sodium chloride solution), we can follow these steps: ### Step-by-Step Solution: 1. **Identify the Components of the Solution**: - The concentrated common salt solution primarily contains sodium chloride (NaCl) and water (H₂O). 2. **Dissociation of Sodium Chloride**: - When sodium chloride is dissolved in water, it dissociates into sodium ions (Na⁺) and chloride ions (Cl⁻): \[ \text{NaCl} \rightarrow \text{Na}^+ + \text{Cl}^- \] 3. **Dissociation of Water**: - Water also dissociates into hydrogen ions (H⁺) and hydroxide ions (OH⁻): \[ \text{H}_2\text{O} \rightarrow \text{H}^+ + \text{OH}^- \] 4. **Electrolysis Process**: - During electrolysis, oxidation occurs at the anode and reduction occurs at the cathode. 5. **Reactions at the Anode**: - At the anode, the oxidation of anions occurs. Between chloride ions (Cl⁻) and hydroxide ions (OH⁻), chloride ions have a lower discharge potential, thus they are discharged first: \[ 2 \text{Cl}^- \rightarrow \text{Cl}_2 + 2 \text{e}^- \] - This reaction produces chlorine gas (Cl₂). 6. **Reactions at the Cathode**: - At the cathode, reduction occurs. Between sodium ions (Na⁺) and hydrogen ions (H⁺), hydrogen ions are discharged first due to their higher tendency to be reduced: \[ 2 \text{H}^+ + 2 \text{e}^- \rightarrow \text{H}_2 \] - This reaction produces hydrogen gas (H₂). 7. **Formation of Sodium Hydroxide**: - After the electrolysis, the remaining ions in the solution are sodium ions (Na⁺) and hydroxide ions (OH⁻). These combine to form sodium hydroxide (NaOH): \[ \text{Na}^+ + \text{OH}^- \rightarrow \text{NaOH} \] 8. **Final Products**: - Therefore, the final products of the electrolysis of concentrated common salt solution are: - Chlorine gas (Cl₂) - Hydrogen gas (H₂) - Sodium hydroxide (NaOH) ### Conclusion: The products of the electrolysis of concentrated common salt solution are chlorine (Cl₂), hydrogen (H₂), and sodium hydroxide (NaOH). ---
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Knowledge Check

  • What wil be the products of electrolysis of an aqueous solution of AgNO_(3) with silver electrodes ?

    A
    Ag from Ag anode dissolves while `Ag^(+)` from solution gets deposited on cathode.
    B
    Ag is liberated at cathode and `O_(2)` is liberated at anode.
    C
    Ag at cathode and nitric acid at anode is liberated.
    D
    No reaction takes place.
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