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Assertion (A): NaOH is a stronger base t...

Assertion (A): NaOH is a stronger base than KOH.
Reason (R ): KOH is more soluble in water than NaOH.

A

If both (A) and (R ) are correct and (R ) is the correct explanation of (A).

B

If both (A) and (R ) are correct, but (R ) is not the correct explanation of (A).

C

If (A) is correct, but (R ) is incorrect.

D

If (A) is incorrect, but (R ) is correct.

Text Solution

AI Generated Solution

The correct Answer is:
To solve the question regarding the assertion and reason, we will analyze both statements step by step. ### Step 1: Analyze the Assertion (A) The assertion states that "NaOH is a stronger base than KOH." To evaluate this, we need to consider the properties of sodium hydroxide (NaOH) and potassium hydroxide (KOH). - **Basicity of Alkali Metal Hydroxides**: In the alkali metal group, the basicity of hydroxides increases as we move down the group. This is due to the decrease in ionization enthalpy and an increase in electropositivity of the metals. Therefore, KOH, being from a lower period than NaOH, is actually a stronger base. **Conclusion for Assertion**: The assertion is **false**. ### Step 2: Analyze the Reason (R) The reason states that "KOH is more soluble in water than NaOH." We need to evaluate the solubility of both compounds. - **Solubility in Water**: Potassium hydroxide (KOH) is indeed more soluble in water compared to sodium hydroxide (NaOH). This higher solubility allows KOH to dissociate more readily in aqueous solutions, contributing to its stronger basic nature. **Conclusion for Reason**: The reason is **true**. ### Step 3: Final Evaluation Since the assertion is false and the reason is true, we can conclude that the correct answer to the question is that the assertion is incorrect while the reason is correct. ### Final Answer The correct answer is: **D** (Assertion is false, Reason is true). ---

To solve the question regarding the assertion and reason, we will analyze both statements step by step. ### Step 1: Analyze the Assertion (A) The assertion states that "NaOH is a stronger base than KOH." To evaluate this, we need to consider the properties of sodium hydroxide (NaOH) and potassium hydroxide (KOH). - **Basicity of Alkali Metal Hydroxides**: In the alkali metal group, the basicity of hydroxides increases as we move down the group. This is due to the decrease in ionization enthalpy and an increase in electropositivity of the metals. Therefore, KOH, being from a lower period than NaOH, is actually a stronger base. **Conclusion for Assertion**: The assertion is **false**. ...
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CENGAGE CHEMISTRY ENGLISH-S-BLOCK GROUP 1 - ALKALI METALS-Exercises Assertion Reasoning
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  2. Assertion (A): Potassium is a stronger reducing agent than sodium. R...

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  3. Assertion (A): NaOH is a stronger base than KOH. Reason (R ): KOH is...

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  4. Assertion (A): Sodium reacts with oxygen to form Na(2)O(2) whereas pot...

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  5. Assertion (A): Aqueous solution of Na(2)CO(3) is alkaline in nature. ...

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  6. Assertion: Lithium resembles magnesium diagonally placed in next group...

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  7. Assertion (A): Alkali metals do not occur in native state. Reason (R...

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  8. Assertion (A) : LiCl is predominantly a covalent compound. Reason (R...

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  9. Assertion (A): Caesium metal when dissolved in liquid amtmonia forms a...

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  10. Assertion (A): Alkali metals dissolve in liquid ammoia to give blue so...

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  11. Assertion (A): Li^(o+) (aq) has large ionic redius than Na^(o+) (aq). ...

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  12. Assertion (A): In rainy season, common salt becomes damp after sometim...

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  13. Assertion (A): Na(2)CO(3) and Li(2)CO(3) are thermally stable. Reaso...

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  14. Assertion (A): Lithium reacts with oxygen to form Li(2)O, but potassiu...

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  15. Assertion (A): Among the alkali metals caesium salts exhibit the maxim...

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  16. Assertion (A): CuCI is more covalent than NaCI. Reason (R ): Na^(o+)...

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  17. A: Sodium ions are discharged when aqueous solution of NaCl is electro...

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  18. Assertion (A): Alkali metlas impart colour to the flame. Reason (R )...

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  19. Assertion (A): Alkali metals are strong reducing agents. Reason (R )...

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  20. Assertion: Potassium is not obtained by the the electrolysis of fused...

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