Home
Class 11
CHEMISTRY
(a). Which alkaline earth metals do not ...

(a). Which alkaline earth metals do not give characteristic colour to the Bunsen flame?
(b). Why alkaline earth metals do not form tripositive ions?
(c ). Why alkaline earth metals are diamagnetic, but alkali metals are paramagnetic?
(d). Why the first inonisation enthaply pf alkaline earth matals is higher than those of corresponding alkali metals?
(e). Why alkaline earth metals are less electropositive than corresponding alkali metals?

Text Solution

Verified by Experts

a. `Be` and `Mg` do not give characteristic colour to the bunsen flame.
B. General electronic configuration of alkaline earth metals is `ns^(2)` preceded by noble gas core. After the removal of two electrons, bipositive cation formed acquires a stable noble gas configuration. for the removal of the third electron, a very large amount of energy is required and that is why alkaline earth metlas do not form tripositive ion, `M^(3+)`.
`underset(2p^(6)3s^(2))(Mg)overset(IE_(1))underset(-e^(Θ))(rarr)underset(2p^(6)3s^(1))(Mg^(o+))overset(IE_(2))underset(-e^(Θ))(rarr)underset(2p^(5)3s^(0))underset(Mg^(3+))underset(-e^(Θ)darrIE_(3))underset("Stable noble gas configuration")underset(2p^(6)3s^(0))(Mg^(2+))`
c. In case of alkaline earth metals, the general electronic configuration is `ns^(2)`. Due to the presence of paired electons in their atoms, alklaline earth metals are diamagnetic. In case of alkali metals, general electronic configuration is `ns^(1)`. Due to the presence of unpaired electron, alklai metals are paramagnetic.
d. Alkaline earth metals have smaller size as compared to corresponding alkali metals due to increases charge, as a result the higer amount of energy is required for the removal of an electorn from the valence shell. that is why the first ionisation enthalpy of alklaline earth metal is higher than the corresponding alklai metal.
e. Alkaline earth metals have smaller size as compared to alkali metals. Hence, valence shell electrons are more tightly bound to the nucles and ionisation entyhalpy of alkaline earth metals is more is more as compared to alkali metals. consequently, they have less tendency to lose valence shell electrons and are less electropositive as compared to alkali metals.
Promotional Banner

Topper's Solved these Questions

  • S-BLOCK GROUP 2 - ALKALINE EARTH METALS

    CENGAGE CHEMISTRY ENGLISH|Exercise Solved Example|6 Videos
  • S-BLOCK GROUP 2 - ALKALINE EARTH METALS

    CENGAGE CHEMISTRY ENGLISH|Exercise Exercises Linked Comprehension|42 Videos
  • S-BLOCK GROUP 1 - ALKALI METALS

    CENGAGE CHEMISTRY ENGLISH|Exercise Archives Subjective|8 Videos
  • SOME BASIC CONCEPTS AND MOLE CONCEPT

    CENGAGE CHEMISTRY ENGLISH|Exercise Archives Subjective|11 Videos

Similar Questions

Explore conceptually related problems

The ionisation enthalpy of alkaline earth metals is

Alkaline earth metals have lower melting point than correspondig alkali metals.

Alkaline earth metals show:-

The first ionization energies of alkaline earth metal are higher than those of the alkali metals. This is because:

Why do alkaline earth metals and their compounds impart characteristic colours to the flame?

Which of the following alkaline earth metals do not impart any color to the flame?

Which alkaline earth metal compound is volatile

The atomic radii of alkaline earth metals are smaller than those of the corresponding alkali metals. Explain, why?

How many alkaline earth metals are known?

The alkaline earth metals forming ionic oxides are