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Alkanline earth metal nitrate (A) on hea...

Alkanline earth metal nitrate `(A)` on heating decompose, leaving a solid residue `(B)` which goes into solution with dilute `HCI`. The solution of `(B)` gives a white precipitate `(C )` is dissolved in dilute `HCl` and the solution is treated with potassium chromae to get yellow precipitate `(D)`. The solution `(B)` with dilute `H_(2)SO_(4)` also gives a white precipitate `(E)` insoluble in diute `HCl` and nitric acid. the precipitate `(E)` is a part of a white pigment lithopone.
The nitrate `(A)` can be confirmed by flame test. The colour imparted by the salt to the Bunsen flame is

A

Yellow

B

Green

C

Blue

D

Red

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The correct Answer is:
To solve the problem, we will break down the steps involved in the decomposition of alkaline earth metal nitrate `(A)` and the subsequent reactions that lead to the formation of various compounds `(B)`, `(C)`, `(D)`, and `(E)`. ### Step-by-Step Solution: 1. **Identify the Alkaline Earth Metal Nitrate `(A)`**: - The alkaline earth metal nitrate that fits the description is **Barium Nitrate (Ba(NO3)2)**. This is because it decomposes upon heating to form a solid residue and gases. 2. **Decomposition of `(A)`**: - When Barium Nitrate is heated, it decomposes according to the reaction: \[ 2 \text{Ba(NO}_3\text{)}_2 \rightarrow 2 \text{BaO} + 4 \text{NO}_2 + \text{O}_2 \] - The solid residue `(B)` left after heating is **Barium Oxide (BaO)**. 3. **Dissolving `(B)` in Dilute HCl**: - Barium Oxide reacts with dilute hydrochloric acid (HCl): \[ \text{BaO} + 2 \text{HCl} \rightarrow \text{BaCl}_2 + \text{H}_2\text{O} \] - The solution now contains **Barium Chloride (BaCl2)**. 4. **Formation of White Precipitate `(C)`**: - When Barium Chloride is treated with a solution that contains sulfate ions (like from sulfuric acid), it forms a white precipitate: \[ \text{BaCl}_2 + \text{Na}_2\text{SO}_4 \rightarrow \text{BaSO}_4 \downarrow + 2 \text{NaCl} \] - The white precipitate `(C)` is **Barium Sulfate (BaSO4)**. 5. **Treatment with Potassium Chromate**: - When the solution of Barium Chloride is treated with potassium chromate (K2CrO4), it forms a yellow precipitate: \[ \text{BaCl}_2 + \text{K}_2\text{CrO}_4 \rightarrow \text{BaCrO}_4 \downarrow + 2 \text{KCl} \] - The yellow precipitate `(D)` is **Barium Chromate (BaCrO4)**. 6. **Formation of White Precipitate `(E)` with Dilute H2SO4**: - When Barium Chloride is treated with dilute sulfuric acid (H2SO4), it forms another white precipitate: \[ \text{BaCl}_2 + \text{H}_2\text{SO}_4 \rightarrow \text{BaSO}_4 \downarrow + 2 \text{HCl} \] - The precipitate `(E)` is again **Barium Sulfate (BaSO4)**, which is insoluble in dilute HCl and nitric acid. 7. **Flame Test for Confirmation of `(A)`**: - The color imparted to the Bunsen flame by Barium Nitrate is **apple green**. ### Final Answer: The color imparted by the salt (Barium Nitrate) to the Bunsen flame is **apple green**.

To solve the problem, we will break down the steps involved in the decomposition of alkaline earth metal nitrate `(A)` and the subsequent reactions that lead to the formation of various compounds `(B)`, `(C)`, `(D)`, and `(E)`. ### Step-by-Step Solution: 1. **Identify the Alkaline Earth Metal Nitrate `(A)`**: - The alkaline earth metal nitrate that fits the description is **Barium Nitrate (Ba(NO3)2)**. This is because it decomposes upon heating to form a solid residue and gases. 2. **Decomposition of `(A)`**: ...
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