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The following compounds have been arrang...

The following compounds have been arranged in order of their increasing stabilities. Identify the correct order.
(I) `K_(2)CO_(3)` (II) `MgCO_(3)`
(III) `CaCO_(3)` (IV) `BeCO_(3)`

A

`I lt II lt III lt IV`

B

`IV lt II lt III lt I`

C

`IV lt II lt I lt III`

D

`II lt IV lt III lt I`

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The correct Answer is:
To determine the correct order of stability for the compounds \( K_2CO_3 \), \( MgCO_3 \), \( CaCO_3 \), and \( BeCO_3 \), we need to analyze the stability of these compounds based on their group classifications and the properties of the cations involved. ### Step-by-Step Solution: 1. **Identify the Groups**: - \( K_2CO_3 \) is a compound of Group 1 (alkali metal). - \( MgCO_3 \), \( CaCO_3 \), and \( BeCO_3 \) are compounds of Group 2 (alkaline earth metals). 2. **Understand Stability Trends**: - Generally, the thermal stability of carbonates increases as you move down the group in the periodic table. This is due to the increase in ionic size and decrease in polarizing power of the cations. - Group 1 carbonates (like \( K_2CO_3 \)) are typically more thermally stable than Group 2 carbonates. 3. **Analyze the Group 2 Carbonates**: - Among the Group 2 carbonates, the stability order is influenced by the size of the cation: - \( BeCO_3 \) is the least stable because beryllium has a small ionic radius and high charge density, leading to a high polarizing power, which destabilizes the carbonate ion. - \( MgCO_3 \) is more stable than \( BeCO_3 \) but less stable than \( CaCO_3 \) due to the increasing ionic size and decreasing polarizing power. - \( CaCO_3 \) is more stable than both \( BeCO_3 \) and \( MgCO_3 \) due to its larger ionic size. 4. **Combine the Information**: - Since \( K_2CO_3 \) is a Group 1 compound, it will be more stable than all Group 2 carbonates. - The order of stability among the Group 2 carbonates is \( CaCO_3 > MgCO_3 > BeCO_3 \). 5. **Final Order of Stability**: - Therefore, the overall order of increasing stability is: \[ BeCO_3 < MgCO_3 < CaCO_3 < K_2CO_3 \] ### Conclusion: The correct order of increasing stability for the compounds is: \[ BeCO_3 < MgCO_3 < CaCO_3 < K_2CO_3 \]

To determine the correct order of stability for the compounds \( K_2CO_3 \), \( MgCO_3 \), \( CaCO_3 \), and \( BeCO_3 \), we need to analyze the stability of these compounds based on their group classifications and the properties of the cations involved. ### Step-by-Step Solution: 1. **Identify the Groups**: - \( K_2CO_3 \) is a compound of Group 1 (alkali metal). - \( MgCO_3 \), \( CaCO_3 \), and \( BeCO_3 \) are compounds of Group 2 (alkaline earth metals). ...
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CENGAGE CHEMISTRY ENGLISH-S-BLOCK GROUP 2 - ALKALINE EARTH METALS-Exercises Single Correct
  1. The basic strength of which hydroxide is maximum

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  2. Of the following , and amphoteric hydroxide is

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  3. The following compounds have been arranged in order of their increasin...

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  4. Magnesium combines with nitrogen to form a nitride, which reacts with ...

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  5. Which has the highest electronegativity?

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  6. Which of the folowing undergoes disproportionation?

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  7. Which of the following is soluble in acetic acid?

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  8. Which of the following fluoride is more soluble in water?

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  9. Why does the solubility of alkaline earth metal carbonates and sulphat...

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  10. Epsom salt's chemical formula is

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  11. Which of the following alkaline earth metal oxide is most basic?

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  12. Which of the following metal reacts with cold H(2)O with the evolution...

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  13. Which of the following salt will give a green colour in fire works?

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  14. Which of the following does not contain the true peroxide ion?

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  15. (a). Mention the most abundant and least abudant alkaline earth meta...

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  16. The hydration energy of Mg^(2+) is larger than that of:

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  17. Which of the following alkaline earth metal carbonate is thermally l...

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  18. The basic chartacter of the alkaline earth metal hydroxides is as foll...

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  19. The carbonate of which of the following cation is soluble in water ?

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  20. Which of the following metal is the most difficult to extract from its...

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