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Assertion (A): BaCO(3) is more soluble i...

Assertion (A): `BaCO_(3)` is more soluble in `HNO_(3)` than in water.
Reason (R ): Carbonate is a weak base and reacts with `H^(o+)` ions to form strong acid causing barium salt to dissociate.

A

If both `(A)` and `(R )` are correct and `(R )` is the correct explanation of `(A)`.

B

If both `(A)` and `(R )` are correct, but `(R )` is not the correct explanation of `(A)`.

C

If `(A)` is correct, but `(R )` is incorrect.

D

If `(A)` is incrrect, but `(R )` is correct.

Text Solution

AI Generated Solution

The correct Answer is:
To solve the given question, we need to analyze the assertion and the reason provided. ### Step-by-Step Solution: 1. **Understanding the Assertion:** - The assertion states that BaCO₃ (barium carbonate) is more soluble in HNO₃ (nitric acid) than in water. - This statement is true. Barium carbonate is indeed more soluble in nitric acid compared to water. 2. **Understanding the Reason:** - The reason provided is that carbonate is a weak base and reacts with H⁺ ions to form a strong acid, which causes barium salt to dissociate. - This statement is also true. When BaCO₃ reacts with H⁺ ions from HNO₃, it forms barium nitrate (Ba(NO₃)₂), carbon dioxide (CO₂), and water (H₂O). The reaction can be represented as: \[ \text{BaCO}_3 + 2\text{HNO}_3 \rightarrow \text{Ba(NO}_3)_2 + \text{CO}_2 + \text{H}_2\text{O} \] - The formation of a soluble barium salt (Ba(NO₃)₂) from the reaction indicates that the dissociation occurs, thus increasing the solubility of BaCO₃ in HNO₃. 3. **Conclusion:** - Since both the assertion and the reason are true, and the reason correctly explains the assertion, we conclude that: - Assertion (A) is true. - Reason (R) is true and is the correct explanation for Assertion (A). ### Final Answer: Both the assertion and reason are correct, and the reason is the correct explanation for the assertion.
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