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Give reasons for the following:...

Give reasons for the following:

A

`BeO` is used as a refractory material.

B

Beryllium halides are polymeric.

C

`Be(OH)_(2)` dissolves in `NaOH`, but `Ca(OH)_(2)` does not

D

On hydrolysis at room temperature, `Mg_(3)N_(2)` gives ammonia, whereas `MgCl_(2)` gives `HCl`.

Text Solution

AI Generated Solution

### Step-by-Step Solution: **1. Beryllium oxide is used as a refractory material.** - **Reason:** Beryllium oxide (BeO) is thermally stable and inert towards chemical reactions due to its high lattice enthalpy. The strong ionic bonds in BeO prevent it from dissociating into its constituent ions, which contributes to its stability at high temperatures. This makes BeO suitable for use as a refractory material, as it can withstand extreme heat without undergoing chemical changes. **2. Beryllium halides are polymeric.** - **Reason:** Beryllium halides, such as beryllium chloride (BeCl2), exhibit polymeric behavior because beryllium has an incomplete octet. To achieve a stable electronic configuration, beryllium atoms can form polymeric chains in the solid state. In the case of BeCl2, the polymeric structure is characterized by 4-electron 3-center (4e-3c) bonds, allowing the formation of a network structure that stabilizes the compound. ...
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CENGAGE CHEMISTRY ENGLISH-S-BLOCK GROUP 2 - ALKALINE EARTH METALS-Ex 5.1Subjective
  1. Give reason for, 'NaHCO(3) is known in solid state but Ca(HCO(3))(2) i...

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  2. Contrast the action of heat on the following with reason: a. Na(2)C...

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  3. Complete the following equations for the reaction between

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  4. The enthlpy of formation of hypothetical CaCl((s)) theoretically found...

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  5. Compare and contrast the chemistry of alkali metal with that of alkali...

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  6. What happens when:

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  7. Describe two important uses of each of the following: (i) caustic soda...

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  8. List the raw materials required in the manufacture of portland cement....

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  9. Name the chief forms of occurrence of magnesium in nature.

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  10. Commerical aluminium always contains some magnesium, name two such all...

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  11. Why is it that the s-block elements never occur free in nature? What a...

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  12. How will you distinguish between: a. Magnesium and strontium b. K(2)...

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  13. Give reasons for the following:

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  14. How is anhydrous magnesium chloride prepared from magnesium chloride h...

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  15. Give reasons for the following:

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  16. Lattice enthalpies of BeF(2),MgF(2),CaF(2) and BaF(2) are -2906,-2610,...

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  17. On treatment with cold water, an element (A) reacted quietly liberatin...

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  18. Give reasons for the following: a. Anhydrous calcium sulphate (anhyd...

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  19. What happens when: SO(2) is passed through limewater.

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  20. Give the chemical formula of the following: a. Plaster of paris, b. ...

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