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Why B-X bond distance in BX(3) is shorte...

Why `B-X` bond distance in `BX_(3)` is shorter than theoretically expected value ?

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To understand why the `B-X` bond distance in `BX3` (where `X` is a halogen) is shorter than the theoretically expected value, we can break down the explanation into several steps: ### Step 1: Understanding the Electronic Configuration of Boron - Boron has an atomic number of 5, and its ground state electronic configuration is `1s² 2s² 2p¹`. This means that in its outer shell, boron has three electrons (two in the `2s` subshell and one in the `2p` subshell). ### Step 2: Excitation of Electrons - When boron forms `BX3`, it can promote one of its `2s` electrons to the `2p` orbital, resulting in an excited state configuration of `2s¹ 2p²`. This configuration allows boron to have three unpaired electrons available for bonding. ...
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CENGAGE CHEMISTRY ENGLISH-P-BLOCK GROUP 13 - BORON FAMILY-Ex 6.1 (Subjective)
  1. Why boron does not exist as B^(3+) ion in solution or in compound ?

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  2. The +1 oxidation state is more stable than +3 oxidation state for thal...

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  3. Aluminium chloride exists as dimer. Give reason.

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  4. Why boron halides do not exists as a dimer. While AlCl(3) exists as Al...

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  5. Give reason for the following: +1 gallium undergoes disproportionat...

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  6. Why boron and aluminium tend to for, covalent compounds ?

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  7. Molten aluminium bromide is a poor conductor of electricity. Give reas...

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  8. Why B-X bond distance in BX(3) is shorter than theoretically expected ...

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  9. Boric acid can be titrated against sodium hydroxide using phenolphthal...

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  10. Which one is more stable in diethy1 ether anhydrous AICI(3) or hydrous...

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  11. How is boron obtained from borax ? Give the chemical reactions involve...

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  12. Unlike ordinary fire, thermite reaction cannot be stopped by pouring w...

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  13. (a) Explain why BF(3) exists whereas BH(3) does not. (b) Compare the...

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  14. State with equations what happens when borax is heated on a platinum w...

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  15. What is inorganic benzene ? Why is it so called ? How will you get it ...

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  16. AlF(3) is insoluble in anhydrous HF but dissolves on addition of NaF. ...

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  17. What do you understand by : Bentonite

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