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AlF(3) is insoluble in anhydrous HF but ...

`AlF_(3)` is insoluble in anhydrous `HF` but dissolves on addition of `NaF. AlF_(3)` precipitates out of resulting solution when gaseous `BF_(3)` is bubbled through. Give reasons.

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To solve the question regarding the solubility of AlF₃ in anhydrous HF and its behavior upon the addition of NaF and BF₃, we can break down the explanation into clear steps. ### Step 1: Understanding the Insolubility of AlF₃ in Anhydrous HF AlF₃ (aluminum trifluoride) is insoluble in anhydrous HF (hydrogen fluoride) due to two main reasons: 1. **Covalent Nature of HF**: Anhydrous HF is a polar covalent compound and does not dissociate into ions. This means it cannot provide the necessary fluoride ions (F⁻) to react with AlF₃. 2. **Strong Hydrogen Bonding**: The strong hydrogen bonding in anhydrous HF prevents it from ionizing, further contributing to the lack of fluoride ions in the solution. ### Step 2: Dissolution of AlF₃ in the Presence of NaF ...
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AlF_(3) is insoluble in anhydrous HF but dissolves on addition of NaF. AlF_(3) precipitates out of the resulting solution when gaseous BF_(3) is bubbled through. Give reasons.

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CENGAGE CHEMISTRY ENGLISH-P-BLOCK GROUP 13 - BORON FAMILY-Ex 6.1 (Subjective)
  1. Why boron does not exist as B^(3+) ion in solution or in compound ?

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  2. The +1 oxidation state is more stable than +3 oxidation state for thal...

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  3. Aluminium chloride exists as dimer. Give reason.

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  4. Why boron halides do not exists as a dimer. While AlCl(3) exists as Al...

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  5. Give reason for the following: +1 gallium undergoes disproportionat...

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  6. Why boron and aluminium tend to for, covalent compounds ?

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  7. Molten aluminium bromide is a poor conductor of electricity. Give reas...

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  8. Why B-X bond distance in BX(3) is shorter than theoretically expected ...

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  9. Boric acid can be titrated against sodium hydroxide using phenolphthal...

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  10. Which one is more stable in diethy1 ether anhydrous AICI(3) or hydrous...

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  11. How is boron obtained from borax ? Give the chemical reactions involve...

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  12. Unlike ordinary fire, thermite reaction cannot be stopped by pouring w...

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  13. (a) Explain why BF(3) exists whereas BH(3) does not. (b) Compare the...

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  14. State with equations what happens when borax is heated on a platinum w...

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  15. What is inorganic benzene ? Why is it so called ? How will you get it ...

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  16. AlF(3) is insoluble in anhydrous HF but dissolves on addition of NaF. ...

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  17. What do you understand by : Bentonite

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