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Which one of following is not an electro...

Which one of following is not an electron deficient compound

A

`BCI_(3)`

B

`AICI_(3)`

C

`B_(2)H_(6)`

D

`Al_(2)CI_(6)`

Text Solution

AI Generated Solution

The correct Answer is:
To determine which of the given compounds is not an electron deficient compound, we need to analyze the electron configuration of each compound in terms of their octet. ### Step-by-Step Solution: 1. **Understanding Electron Deficiency**: - Electron deficient compounds are those that do not have a complete octet of electrons in their valence shell. This means they have fewer than 8 electrons around the central atom. 2. **Analyzing BCl3**: - BCl3 (Boron trichloride) has boron as the central atom. Boron has 3 valence electrons and forms three bonds with chlorine atoms. - Total electrons around boron = 3 (from boron) + 3 (one from each Cl) = 6 electrons. - Since boron has only 6 electrons, BCl3 is an electron deficient compound. 3. **Analyzing AlCl3**: - AlCl3 (Aluminum chloride) has aluminum as the central atom. Aluminum has 3 valence electrons and forms three bonds with chlorine atoms. - Total electrons around aluminum = 3 (from aluminum) + 3 (one from each Cl) = 6 electrons. - Thus, AlCl3 is also an electron deficient compound. 4. **Analyzing B2H6**: - B2H6 (Diborane) consists of two boron atoms and six hydrogen atoms. Each boron atom shares its electrons with hydrogen. - Each boron atom effectively has 6 electrons (3 from bonds with H) and does not complete its octet. - Therefore, B2H6 is also an electron deficient compound. 5. **Analyzing Al2Cl6**: - Al2Cl6 (Dimer of Aluminum chloride) consists of two aluminum atoms and six chlorine atoms. In this compound, the two AlCl3 units combine to form a dimer. - In this structure, each aluminum atom can share electrons with the chlorine atoms through coordinate bonds, allowing them to achieve a complete octet. - Therefore, Al2Cl6 is not an electron deficient compound because it can achieve an octet through bonding. ### Conclusion: The compound that is **not** electron deficient is **Al2Cl6**. ### Final Answer: **Al2Cl6** is not an electron deficient compound. ---
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