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Sulphur on reaction with concentrated HN...

Sulphur on reaction with concentrated `HNO_3`. Gives `(A)` which reacts with reacts with `NaOH` gives `(B).(A)` and `(B)` are

A

`H_2 SO_3, Na_2 S_2 O_3`

B

`NO_2, Na_2 S`

C

`H_2 SO_4, Na_2 SO_4`

D

`H_2 S_2 O_3, Na_2 S_2 O_3`

Text Solution

AI Generated Solution

The correct Answer is:
To solve the question, we need to analyze the reaction of sulfur with concentrated nitric acid (HNO3) and the subsequent reaction with sodium hydroxide (NaOH). ### Step-by-step Solution: 1. **Identify the Reaction of Sulfur with Concentrated HNO3**: - When sulfur (S) reacts with concentrated nitric acid (HNO3), it is oxidized. The main product of this reaction is sulfuric acid (H2SO4) and nitrogen dioxide (NO2) is also produced as a byproduct. - The balanced chemical equation for this reaction is: \[ S + 6HNO_3 \rightarrow H_2SO_4 + 6NO_2 + 2H_2O \] - Here, the product (A) is **H2SO4** (sulfuric acid). 2. **Reaction of H2SO4 with NaOH**: - The next step is to consider the reaction of sulfuric acid (H2SO4) with sodium hydroxide (NaOH). This is a typical acid-base neutralization reaction. - The balanced equation for this reaction is: \[ H_2SO_4 + 2NaOH \rightarrow Na_2SO_4 + 2H_2O \] - In this reaction, sodium sulfate (Na2SO4) is formed as the product (B). 3. **Final Products**: - From the above reactions, we conclude that: - Product (A) is **H2SO4** (sulfuric acid). - Product (B) is **Na2SO4** (sodium sulfate). ### Conclusion: Thus, the answer to the question is: - (A) = H2SO4 - (B) = Na2SO4

To solve the question, we need to analyze the reaction of sulfur with concentrated nitric acid (HNO3) and the subsequent reaction with sodium hydroxide (NaOH). ### Step-by-step Solution: 1. **Identify the Reaction of Sulfur with Concentrated HNO3**: - When sulfur (S) reacts with concentrated nitric acid (HNO3), it is oxidized. The main product of this reaction is sulfuric acid (H2SO4) and nitrogen dioxide (NO2) is also produced as a byproduct. - The balanced chemical equation for this reaction is: \[ ...
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