Home
Class 12
CHEMISTRY
(a) Fluorine cannot be prepared from flu...

(a) Fluorine cannot be prepared from fluorides by chemical oxidation. Why?
(b) Anhydrous `HCl` is bad conductor of electricity while aqueous `HCl` is a good conductor.

Text Solution

Verified by Experts

(a) The standard reduction potential of fluorine is maximum. Thus, it cannot be oxidised by any other reagent. Fluoride ion is very stable due to small size and high electronegativity of fluorine atom. Thus, fluorine cannot be prepared from fluorides by chemical oxidation.
(b) In anhydrous state, `HCl` is a covalent molecule, hence bad conductor of electricity. Whereas , in aqueous state, `HCl` ionises and acts as good conductor.
`HCl+H_(2)O rarr H_(3)O^(o+)+Cl^(Ө)`
(c ) Hypo solution i.e. sodium thiosulphate, `Na_(2)S_(2)O_(3).5H_(2)O` reacts with iodine to form water soluble colourless sodium tetrathionate and sodium iodide.
`{:(2Na_(2)S_(2)O_(3)+I_(2)to2NaI+Na_(2)S_(4)O_(6)),(or 2S_(2)O_(3)^(2-)toS_(4)O_(6)^(2-)+2e^(Ө)),(I_(2)+2e^(Ө)to2I^(Ө)),(ulbar(2S_(2)O_(3)^(2-)+I_(2)toS_(4)O_(6)^(2-)+2I^(Ө))):}`
Promotional Banner

Topper's Solved these Questions

  • P-BLOCK GROUP 17 ELEMENTS - THE HALOGEN FAMILY

    CENGAGE CHEMISTRY ENGLISH|Exercise Solved Example|7 Videos
  • P-BLOCK GROUP 17 ELEMENTS - THE HALOGEN FAMILY

    CENGAGE CHEMISTRY ENGLISH|Exercise Exs 4.1 (Subjective)|16 Videos
  • P-BLOCK GROUP 16 ELEMENTS - THE OXYGEN FAMILY

    CENGAGE CHEMISTRY ENGLISH|Exercise Archives Subjective|10 Videos
  • P-BLOCK GROUP 18 ELEMENTS - THE INERT GASES

    CENGAGE CHEMISTRY ENGLISH|Exercise Ex 5.1 (Objective)|14 Videos

Similar Questions

Explore conceptually related problems

Given reasons in one or two sentences. “Anhydrous HCl is a bad conductor of electricity but aqueous HCl is a good conductor.”

Give reasons in one or two sentences :" anhydrous HCl is a bad conductor of electricity but aqueous HC l is a good conductor. "

Give reason why ? Anhydrous HCl is a poor conductor while aqueous HCl is an excellent conductor .

Why is diamond a bad conductor of electricity but a good conductor of heat?

Why is magnesium a good conductor of electricity ?

Explain why : hydrochloric acid is a good conductor of electricity.

Why CaCl_(2) and NaCl are bad conductor of electricity in the solid state.

Explain why the covalent solids are bad conductors of electricity.

Copper is a good conductor of electricity, but it is a non-electrolyte. Why?

Copper is a good conductor of electricity but it is not considered as an electrolyte .Why ?