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Size of the iodine species following the...

Size of the iodine species following the order:

A

`I^(o+)gtI^(Theta)gtI`

B

`IgtI^(o+)gtI^(Theta)`

C

`IgtI^(Theta)gtI^(o+)`

D

`I^(Theta)gtIgtI^(o+)`

Text Solution

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The correct Answer is:
To determine the size of iodine species (I, I-, and I+), we need to analyze how the addition or removal of electrons affects the size of the species. ### Step-by-Step Solution: 1. **Understanding the Species**: - We have three species to compare: I (iodine atom), I- (iodide ion), and I+ (iodine cation). - I is the neutral atom, I- is the anion formed by gaining an electron, and I+ is the cation formed by losing an electron. 2. **Analyzing I- (Iodide Ion)**: - When iodine gains an electron to become I-, it experiences an increase in electron-electron repulsion due to the additional electron. - This repulsion causes the outer electrons to spread out more, resulting in an increase in size. - Therefore, I- will have the largest size among the three species. 3. **Analyzing I (Neutral Iodine Atom)**: - The neutral iodine atom (I) has a balanced number of protons and electrons. - It has a smaller size compared to I- because it does not have the extra electron that contributes to repulsion. - Thus, the size of I is smaller than that of I-. 4. **Analyzing I+ (Iodine Cation)**: - When iodine loses an electron to form I+, the number of electrons decreases, which reduces electron-electron repulsion. - With less repulsion, the remaining electrons can be pulled closer to the nucleus, resulting in a decrease in size. - Therefore, I+ will have the smallest size among the three species. 5. **Establishing the Order**: - Based on the analysis: - I- > I > I+ - This means the order of size from largest to smallest is I-, I, I+. ### Final Answer: The size of the iodine species follows the order: **I- > I > I+**.

To determine the size of iodine species (I, I-, and I+), we need to analyze how the addition or removal of electrons affects the size of the species. ### Step-by-Step Solution: 1. **Understanding the Species**: - We have three species to compare: I (iodine atom), I- (iodide ion), and I+ (iodine cation). - I is the neutral atom, I- is the anion formed by gaining an electron, and I+ is the cation formed by losing an electron. ...
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CENGAGE CHEMISTRY ENGLISH-P-BLOCK GROUP 17 ELEMENTS - THE HALOGEN FAMILY-Exercises (Single Correct)
  1. Which one of the following halogen acids has the lowest melting point ...

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  2. Which of the following halogen acids has the highest boiling point ?

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  3. Size of the iodine species following the order:

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  4. volatile nature of halogens is because

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  5. Which of the following will displace the halogen form the solution of ...

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  6. Which one of the followign is the most basic ?

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  7. Euchlorine is a mixture of

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  8. On heating NaX with H(2)SO(4) and MnO(2) the halogens that cannot be p...

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  9. In the reaction: 3Br(2)+6OH^(Theta)rarr 5Br^(Theta)+BrO(3)^(Theta)+3H...

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  10. Ticture of iodine contains

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  11. In the reaction I(2)+2OH^(Theta)rarr I^(Theta)+IO^(Theta)+H(2)O I(2) i...

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  12. Estimation of reducing substances by the use of standard I(2), I(2)+...

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  13. Estimation of oxidising substance involving the liberation of I(2) and...

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  14. HCI and HF are prepared by heating their salt (NaCI and CaF(2)) with c...

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  15. HBr and HI may be obtained by heating bromide and iodine with syrupy p...

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  16. On passign CI(2) water in a mixture of KBr and KI solution in contact ...

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  17. Which of the following is soluble in water ?

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  18. A greenish yellow gas reacts with an alkali metal hydroxide to form a ...

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  19. When chlorine water is added to an aqueous solution of sodium iodide i...

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  20. For (A)+K(2)CO(3)+"air" overset(Heat)rarr(B) (B)+Cl(2)rarr(C)pink ...

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