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Estimation of reducing substances by the...

Estimation of reducing substances by the use of standard `I_(2)`,
`I_(2)+2S_(2)O_(3)^(2-)rarr S_(4)O_(6)^(2-)+2I^(Theta)` is called

A

Ioimetry

B

Iodometry

C

Oxidising

D

Reducing

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To solve the question regarding the estimation of reducing substances using standard iodine (I₂), we will analyze the provided reaction and the definitions of related terms. ### Step-by-Step Solution: 1. **Understanding the Reaction**: The reaction given is: \[ I_2 + 2 S_2O_3^{2-} \rightarrow S_4O_6^{2-} + 2 I^{-} \] In this reaction, iodine (I₂) is reacting with thiosulfate ions (S₂O₃²⁻) to produce tetrathionate ions (S₄O₆²⁻) and iodide ions (I⁻). 2. **Identifying the Process**: The process involves the use of iodine (I₂) to estimate the amount of reducing substances present in a solution. The iodine acts as an oxidizing agent and gets reduced to iodide ions (I⁻) in the process. 3. **Differentiating Between Terms**: - **Iodimetry**: This term refers to the estimation of reducing agents by using iodine (I₂) as a titrant. It involves the direct titration of reducing substances with standard iodine. - **Iodometry**: This term refers to the estimation of oxidizing agents by adding iodide ions to form iodine, which is then titrated. Here, iodine acts as an oxidizing agent. 4. **Conclusion**: Since the question specifically asks for the estimation of reducing substances using standard iodine, the correct term for this process is **Iodimetry**. ### Final Answer: The estimation of reducing substances by the use of standard I₂ is called **Iodimetry**. ---
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I_(2)+S_(2)O_(3)^(2-) to I^(-)+S_(4)O_(6)^(2-)

I_(2)+S_(2)O_(3)^(2-) to I^(-)+S_(4)O_(6)^(2-)

In the reaction, I_(2)+2S_(2)O_(3)^(2-) rarr 2I^(-)+S_(4)O_(6)^(2-) .

Estimation of oxidising substance involving the liberation of I_(2) and subsequent volumetric estimation of I_(2) are refferred to as 2Cu^(2+)+4I^(Theta)rarr Cu_(2)I_(2)+I_(2) I_(2)+ S_(2)O_(3)^(2-)rarr S_(4)O_(6)^(2-)+2I^(Theta)

(a). IF both (A) and (R) are correct and (R) is the correct explanation of (A). (b). If both (A) and (R) are correct but (R) is not the correct explanation of (A). (c). If (A) is correct, but (R) is incorrect. (d). If (A) is incorrect, but (R) is correct. ltbr. (e) if both (A) and (R) are incorrect. Q. Assertion (A): Estimation of reducing substance by the use of standard I_(2) is called iodometry. Reason (R): in the reaction I_(2)+S_(2)O_(3)^(2-)toS_(4)O_(6)^(2-)+2I^(ɵ) The n factor of S_(2)O_(3)^(2-) is one.

Consider the redox reaction 2S_(2)O_(3)^(2-)+I_(2)rarrS_(4)O_(6)^(2-)+2I^(ө)

In the reaction, I_(2)+2S_(2)O_(3)^(2-) rarr 2I^(-)+S_(4)O_(6)^(2-) . Equivalent wieght of iodine will be equal to

In the reaction, I_(2)+2S_(2)O_(3)^(2-) rarr 2I^(-)+S_(4)O_(6)^(2-) . Equivalent wieght of iodine will be equal to

The order of increasing oxidation number of S in S_(8),S_(2)O_(8)^(-2),S_(2)O_(3)^(2-),S_(4)O_(6)^(-2) is given below -

A constant current was flowen for 1 mi n through a solution of Kl . At the end of experiment, liberated I_(2) consumed 150mL of 0.01M solution of Na_(2)S_(2)O_(3) following the reaction : I_(2)+2S_(2)O_(3)^(2-) rarr 2I^(c-)+S_(4)O_(6)^(2-) What was the average rate of current flow in ampere ?

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