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KCIO(3) on reaction with SO(2) gives (A)...

`KCIO_(3)` on reaction with `SO_(2)` gives (A) and on reactionwith conc. `H_(2)SO_(4)` gives (B).(A) and (B) are

A

`KCI,HCI_(4)`

B

`CI_(2),CIO_(2)`

C

`KCI,HCIO_(3)`

D

`CI_(2),HCIO_(4)`

Text Solution

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The correct Answer is:
To solve the question, we need to analyze the reactions of potassium chlorate (KClO₃) with sulfur dioxide (SO₂) and concentrated sulfuric acid (H₂SO₄). ### Step 1: Reaction of KClO₃ with SO₂ When KClO₃ reacts with SO₂, the reaction can be represented as follows: \[ \text{KClO}_3 + \text{SO}_2 \rightarrow \text{KCl} + \text{SO}_3 \] In this reaction, potassium chlorate (KClO₃) is reduced, and sulfur dioxide (SO₂) acts as a reducing agent. The product formed from this reaction is potassium chloride (KCl). **Product A:** KCl ### Step 2: Reaction of KClO₃ with concentrated H₂SO₄ Now, let's consider the reaction of KClO₃ with concentrated sulfuric acid (H₂SO₄). The reaction can be represented as follows: \[ \text{KClO}_3 + \text{H}_2\text{SO}_4 \rightarrow \text{HClO}_4 + \text{KHSO}_4 + \text{ClO}_2 + \text{H}_2\text{O} \] In this reaction, potassium chlorate reacts with concentrated sulfuric acid to produce several products, including perchloric acid (HClO₄). **Product B:** HClO₄ ### Conclusion From the reactions we analyzed: - Product A (from the reaction with SO₂) is KCl. - Product B (from the reaction with concentrated H₂SO₄) is HClO₄. Thus, the final answer is: - (A) = KCl - (B) = HClO₄

To solve the question, we need to analyze the reactions of potassium chlorate (KClO₃) with sulfur dioxide (SO₂) and concentrated sulfuric acid (H₂SO₄). ### Step 1: Reaction of KClO₃ with SO₂ When KClO₃ reacts with SO₂, the reaction can be represented as follows: \[ \text{KClO}_3 + \text{SO}_2 \rightarrow \text{KCl} + \text{SO}_3 \] In this reaction, potassium chlorate (KClO₃) is reduced, and sulfur dioxide (SO₂) acts as a reducing agent. The product formed from this reaction is potassium chloride (KCl). ...
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CENGAGE CHEMISTRY ENGLISH-P-BLOCK GROUP 17 ELEMENTS - THE HALOGEN FAMILY-Exercises (Single Correct)
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  2. Fluorine on reaction with KIO(3(aq)) gives (A) and on reaction with KH...

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  3. KCIO(3) on reaction with SO(2) gives (A) and on reactionwith conc. H(2...

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  5. 10 g of bleaching powder on reaction with KI required 50 mL of 2N hypo...

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  6. HCIO(4)+P(2)O(5)rarr(A)+(B) (A) and (B) are

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  7. AgCOP(3) + (A) to (B) + (C ) + (D) The substances (A), (B), (C ) a...

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  8. Select the correct stattement(s):

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  9. Which one of the following pairs of reactantas does not form oxygen wh...

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  10. One atom of …….. combines with one atom of bromine.

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  11. Which bond has the greatest polarity ?

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  12. Bleaching properties of bleaching powder are due to its

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  13. Bleaching powder is a mixture of

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  14. One can draw the map of a building on a glass plate by

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  15. The colour of I(2) is violet because it

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  16. The boiling points of halogens increase with increase in molecular wei...

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  17. The tetrahedral nature of the three bonds in a chlorate ion (CIO(3)^(T...

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  18. The catalyst used in the Deacon's process for the manufacture of chlor...

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  19. Which one of the following acts as an antichlor ?

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