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Predict the order of Delta(0)for the fol...

Predict the order of `Delta_(0)`for the following compounds
(a) `[Fe(H_(2)O))_(6)]^(2+)`
(II) `[Fe(CN)_(2)(H_(2)O))_(4)]`
(III) `[fe(CN)_(4)(H_(2)O))_(2)]^(2-)`
(a) `delta_(0)ltDelta_(0)(II)ltdelta_(0)(III)`
(b) `delta_(0)ltDelta_(0)(I)ltdelta_(0)(III)`
(c ) `delta_(0)ltDelta_(0)(III)ltdelta_(0)(II) ltDelta_(0)(I)`
`delta_(0)ltDelta_(0)(II)ltdelta_(0)(III)ltDelta_(0)(I)` .

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The correct Answer is:
To predict the order of `Delta_(0)` for the given coordination compounds, we need to analyze the ligands and their field strengths, as well as the electronic configurations of the metal ions in these complexes. ### Step-by-Step Solution: 1. **Identify the Metal Ion and Its Oxidation State:** - For all three complexes, the metal ion is Iron (Fe). - In `[Fe(H₂O)₆]²⁺`, the oxidation state of Fe is +2. - In `[Fe(CN)₂(H₂O)₄]`, the oxidation state of Fe is also +2. - In `[Fe(CN)₄(H₂O)₂]²⁻`, the oxidation state of Fe is +2 as well. 2. **Determine the Electron Configuration of Fe²⁺:** - The atomic number of Fe is 26. For Fe²⁺, the electron configuration is: - 1s² 2s² 2p⁶ 3s² 3p⁶ 3d⁶ - Thus, Fe²⁺ has 6 electrons in the 3d subshell. 3. **Analyze the Ligands:** - **H₂O** is a weak field ligand. - **CN⁻** is a strong field ligand. 4. **Calculate CFSE for Each Complex:** - **(I) `[Fe(H₂O)₆]²⁺`:** - With 6 H₂O ligands (weak field), the configuration is t₂g⁴ e₁. - CFSE = (-0.4 Δ₀ × 4) + (0.6 Δ₀ × 2) = -0.4 Δ₀ × 4 + 0 = -1.6 Δ₀. - **(II) `[Fe(CN)₂(H₂O)₄]`:** - With 2 CN⁻ (strong field) and 4 H₂O (weak field), the configuration is t₂g⁶. - CFSE = (-0.4 Δ₀ × 6) = -2.4 Δ₀. - **(III) `[Fe(CN)₄(H₂O)₂]²⁻`:** - With 4 CN⁻ (strong field) and 2 H₂O (weak field), the configuration is t₂g⁶. - CFSE = (-0.4 Δ₀ × 6) = -2.4 Δ₀. 5. **Order of `Delta_(0)`:** - Based on the CFSE values calculated: - For (I): CFSE = -1.6 Δ₀ - For (II): CFSE = -2.4 Δ₀ - For (III): CFSE = -2.4 Δ₀ - The order of `Delta_(0)` based on CFSE values is: - `Delta_(0)(I) > Delta_(0)(II) = Delta_(0)(III)` ### Final Answer: The correct order of `Delta_(0)` for the given compounds is: **(a) `Delta_(0)(I) > Delta_(0)(II) = Delta_(0)(III)`**

To predict the order of `Delta_(0)` for the given coordination compounds, we need to analyze the ligands and their field strengths, as well as the electronic configurations of the metal ions in these complexes. ### Step-by-Step Solution: 1. **Identify the Metal Ion and Its Oxidation State:** - For all three complexes, the metal ion is Iron (Fe). - In `[Fe(H₂O)₆]²⁺`, the oxidation state of Fe is +2. - In `[Fe(CN)₂(H₂O)₄]`, the oxidation state of Fe is also +2. ...
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