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The complexes [Co(NH(3))(6)][Cr(CN)(6)] ...

The complexes `[Co(NH_(3))_(6)][Cr(CN)_(6)]` and `[Cr(NH_(3))_(6)]`  `[Co(CN)_(6)]` are the examples of which type of isomerism?

A

Linkage isomers

B

Ionisation isomers

C

Coordination isomers

D

None of these

Text Solution

Verified by Experts

The correct Answer is:
C
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[Cr(CN)_(6)][Co(NH_(3))_(6)] contains

coordination compounds often show various types of isomerism. The isomerism can be categorized in two main types (a) structural isomerism (b) stereo or space isomerism Structural isomerism arises due to the difference in structures of coordination-sempounds while stereo or space isomerism arises on account of the different positions and arrangements of ligands (atoms or groups) in space around the metal lonStructural isomerism can be classified in following types (i) tonization isomers- which give different ions in solution, e.g. [CoBr(NH_(3))_(5)]]SO_(4) and [Co(SO_(4))_(5)(NH_(3))_(5)]Br Hydrate isomers which differ in H_(2)O as ligand or as hydration, e.g. [Cr(H_(2)O)_(5)]CI_(2)(H_(2)O)]Cl_(2).H_(2)O[CrCl_(2)(H_(2)O)]CI.2H_(2)O (iii) Linkage isomers, which differ in atom linked to 'metal atom, e.g. [CO(NO_(2))(NH_(3))_(5)]^(2+) and CO(ONO)(NH_(3))_(6)]^(2+) Coordination isomers- which involve interchange of ligands, e.g. [Co(NH_(3))_(6)] [Cr(CN)_(6)] and [Cr(NH_(3))_(6)] [Co(CN)_(6)] (v) Coordination position isomerism-which arises in the bridged complexes due to the difference in the attachment of ligands with the metal atoms QThe compounds [Cr(H_(2)O_(6)]Cl_(3)[Cr(H_(2)O)_(5)CI]Cl_(2).H_(2)O and [Cr(H_(2)O)_(4)Cl_(2)]Cl2H_(2)O exhibit

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Two complexes [Cr(H_(2)O_(6))_(6)]Cl_(3) and [Cr(NH_(3))_(6)]Cl_(3) (B) are violet and yellow coloured, respectively. The incorrect statement regarding them is :

Name of the type of isomerism exhibited by the following pairs of compounds : [Co(NH_(3))_(6) [Cr(CN)_(6)] and [Cr(NH_(3))_(6)] [Co(CN)_(6)]

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[Cr(NH_(3))_(6)]^(3+)+6HCl to Cr^(3+)(aq)+6NH_(4)Cl

Given complexes are low spin complexes [V(CN)_(6)]^(4-) [Cr(NH_(3))_(6)]^(2+) [Ru(NH_(3))_(6)]^(3+) [Fe(CN)_(6)]^(4-) Then of magnetic (mu) for Fe^(2+),Cr^(+3),Ru^(3+) is

Given complexes are low spin complexes [V(CN)_(6)]^(4-) [Cr(NH_(3))_(6)]^(2+) [Ru(NH_(3))_(6)]^(3+) [Fe(CN)_(6)]^(4-) Then of magnetic (mu) for Fe^(2+),Cr^(+3),Ru^(3+) is

CENGAGE CHEMISTRY ENGLISH-COORDINATION COMPOUNDS-Exercises Single Correct (Isomerism)
  1. EAN of Fe in [Fe(C(2)O(4)(3)]^(3-) is .

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  2. The EAN of Fe atom in .

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  3. The complexes [Co(NH(3))(6)][Cr(CN)(6)] and [Cr(NH(3))(6)]  [Co(CN)(6)...

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  4. The Type of isomerism present in pentaammine nitro chromium(III) perch...

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  5. Which one of the following has largest number of isomers ? (R = alkyl ...

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  6. [Cr(NH(3))(5)NO(2)]SO(4) and [Cr(NH(3))(5)ONO]SO(4) are related to eac...

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  7. Which one of the following will be able to show geometrical isomerism ...

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  8. The number of geometrical and optical isomers of [Cr(NH(3))(3)(NO(3)...

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  9. Both geometrical and optical isomerism are shown by

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  10. [Co(C(2)O(4))(3)]^(3-) is a

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  11. Which one of the following octahedral complexes will not show geometri...

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  12. Facial-meridional isomers is associated with which one of the followin...

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  13. The total number of possibel coordination isomer for the given compoun...

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  14. The following complexs are given? trans-[Co(NH(3))(4)1(2)]^(o+) ci...

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  15. The following represents a pair of enantiomers:

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  16. The compounds [PtBr(2)(NH(3))(2)] can form .

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  17. The compound[CrCl(2)(NH(3))(2)(en)] can form .

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  18. One mole of complex compound Cr(NH(3))(5)CI(3) gives 3 moles of ions o...

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  19. Which of the following will show optical isomerism? .

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  20. In which of the following pairs both the complex's show optical isomer...

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