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The total number of possibel coordinatio...

The total number of possibel coordination isomer for the given compounds `[Pt(NH_(3))(4)Br_(2)][PtBr_(4)]` is .

A

`2`

B

`4`

C

`5`

D

`3`

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AI Generated Solution

The correct Answer is:
To determine the total number of possible coordination isomers for the given compounds \([Pt(NH_3)_4Br_2]\) and \([PtBr_4]\), we will follow these steps: ### Step 1: Identify the Coordination Compounds We have two coordination compounds: 1. \([Pt(NH_3)_4Br_2]\) - This is a complex with 4 ammonia (NH3) ligands and 2 bromine (Br) ligands. 2. \([PtBr_4]\) - This is a complex with 4 bromine (Br) ligands. ### Step 2: Understand Coordination Isomers Coordination isomers occur when there is an interchange of ligands between the coordination spheres of the metal centers. In this case, we can exchange the ligands between the two complexes. ### Step 3: Determine Possible Isomers For the complex \([Pt(NH_3)_4Br_2]\), we can have the following coordination isomers by exchanging the ligands: 1. **Isomer 1**: \([Pt(NH_3)_4Br_2]\) - No exchange. 2. **Isomer 2**: \([Pt(NH_3)_3Br_3]\) - One NH3 ligand is replaced by Br. 3. **Isomer 3**: \([Pt(NH_3)_2Br_4]\) - Two NH3 ligands are replaced by Br. 4. **Isomer 4**: \([Pt(NH_3)Br_5]\) - Three NH3 ligands are replaced by Br. ### Step 4: Count the Isomers From the above analysis, we can see that there are 4 distinct coordination isomers for the complex \([Pt(NH_3)_4Br_2]\). ### Step 5: Conclusion Thus, the total number of possible coordination isomers for the given compounds is 4. ### Final Answer The total number of possible coordination isomers for the given compounds \([Pt(NH_3)_4Br_2]\) and \([PtBr_4]\) is **4**. ---

To determine the total number of possible coordination isomers for the given compounds \([Pt(NH_3)_4Br_2]\) and \([PtBr_4]\), we will follow these steps: ### Step 1: Identify the Coordination Compounds We have two coordination compounds: 1. \([Pt(NH_3)_4Br_2]\) - This is a complex with 4 ammonia (NH3) ligands and 2 bromine (Br) ligands. 2. \([PtBr_4]\) - This is a complex with 4 bromine (Br) ligands. ### Step 2: Understand Coordination Isomers ...
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CENGAGE CHEMISTRY ENGLISH-COORDINATION COMPOUNDS-Exercises Single Correct (Isomerism)
  1. Which one of the following will be able to show geometrical isomerism ...

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  2. The number of geometrical and optical isomers of [Cr(NH(3))(3)(NO(3)...

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  3. Both geometrical and optical isomerism are shown by

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  4. [Co(C(2)O(4))(3)]^(3-) is a

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  5. Which one of the following octahedral complexes will not show geometri...

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  6. Facial-meridional isomers is associated with which one of the followin...

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  7. The total number of possibel coordination isomer for the given compoun...

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  8. The following complexs are given? trans-[Co(NH(3))(4)1(2)]^(o+) ci...

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  9. The following represents a pair of enantiomers:

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  10. The compounds [PtBr(2)(NH(3))(2)] can form .

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  11. The compound[CrCl(2)(NH(3))(2)(en)] can form .

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  12. One mole of complex compound Cr(NH(3))(5)CI(3) gives 3 moles of ions o...

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  13. Which of the following will show optical isomerism? .

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  14. In which of the following pairs both the complex's show optical isomer...

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  15. Which of the following shows maximum number of isomers ?

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  16. The possible number of the optical isomers in [Cr(en)(2)CI(2)]^(o+) is...

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  17. Which of the following molecules(s)is//are not showing optical isomeri...

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  18. Which of the following will give a pair of enantiomorphs?

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  19. Both Cr^(3+) and Pt^(4+) have a coordination number of 6 Which of the ...

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  20. Select the correct statement for [M(AB)b(2)cd] .

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