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a. While testing oxalate, gas obtained ...

a. While testing oxalate, gas obtained burns with a blue flame intially but is put off instantly even as gas appears coming. Explain.
b. `I^(Theta)` also interfere in the 'Ring Test' of `NO_(3)^(Theta)` suggest a chemical reagent that removed `I^(Theta)`

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`AgI lt AgBr lt AgCI lt AgF`
b. Boll the mixture `NH_(4)O_(2)^(Theta)` is decomposed as `N_(2)`
`NaNO_(2) + NH_(4)CI overset(Delta) to NaCI + N_(2) uarr + 2H_(2)O`
c. `H_(2) C_(2)O_(4) overset(Delta) to H_(2)O_((1)) + CO_(2(g))`
d. `HgCI_(2)` removes `I^(Theta)`as `HgI_(2)`
`HgCI_(2) + 2I^(Theta) rarr underset("Orange ppt")(HgI_(2) uarr + 2CI^(Theta)) `
e. (A) `NH_(4)CI (B): HCI (C ): NH_(3)`
f. Reducin g power `I^(Theta) gt Br^(Theta) gt CI^(Theta) gt F^(Theta)` Add `CI_(2)` and `CHCI_(3)` into mixture of `I^(Theta)` and `Br^(Theta)`
`2I^(Theta) CI_(2) rarr underset("Violet")(I_(2) +) 2CI^(Theta)`
`2Br^(Theta) + CI_(2) rarr underset("Orange yellow")(Br_(2)) + 2CI^(Theta)`
`Br^(Theta)` will be also oxides `I^(Theta)` to `I^(Theta)` .Thus first there will be violet colour in `CGCI_(3)` layer Extract aq layer (containing `Br^(Theta))` and repeat adding `CI_(2)` water and `CHCI_(3)` orange -yellow colour in `CHO_(3)` layer condifirms `Br^(Theta)`
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CENGAGE CHEMISTRY ENGLISH-QUALITATIVE INORGANIC SALT ANALYSIS-Viva Voce Questions And Part-C (Analysis Of Cations)
  1. a. While testing oxalate, gas obtained burns with a blue flame intial...

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  2. Why is it necessary to prepare original solution for the detection of ...

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  3. Why do we not prefer to prepare original solution of cations in conc....

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  4. What is solubility product? Explain its importance in qualitative anal...

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  5. What is the basis of classification of cations into different group ?

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  6. Why are only Pb^(2+),Ag^(o+) and Hg(2)^(2+) ions precipitated in group...

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  7. Why is lead placed in group I as well in II?

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  8. Is it necessary to acidify a solution before group II cations are prec...

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  9. Give the reason for the formation of a light yellow or white ppt. in t...

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  10. Why do we Prefer HCl for preparing solution of cations?

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  11. Is it advisable to use conc. HCI in place of dilute HCI for preparing ...

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  12. Why is it essential to boil off H(2)S gas before proceeding to group I...

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  13. Can the solution be acidified with HNO(3) in group II before passing H...

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  14. What can it be, if the precipitate of group I is soluble in hot water ...

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  15. Why do we not prefer to prepare original solution of cations in conc....

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  16. Group I filtrate is made moderately acidic before proceeding to group ...

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  17. Why do we add excess of NH(4)Cl and NH(4)OH in the precipitation of gr...

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  18. Why do we add excess of NH(4)Cl and NH(4)OH in the precipitation of gr...

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  19. Why is it essential to oxidise ferrous salt to ferric salt in group II...

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  20. Can NH(4)Cl be replaced by any other ammonium salt for the precipitati...

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  21. How will you distinguish between ferrous and ferric salts?

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