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i.(A) overset(Delta)to glassy traparent...

i.(A) `overset(Delta)to ` glassy traparent beat (B) on platinum wire
(B) `+ CuSO_(4) rarr ` coloured bead(C )
ii `underset((D))((A))+conc. H_(2)SO_(4)+CH_(3)CH_(2)OH overset("ignite")rarr` green flame
iv.Aqueous solution (A) is alkline
Identify A .

A

`NaNH_(4)HPO_(4).4H_(2)O`

B

`Na_(2)B_(4)O_(7).10H_(2)O`

C

`CuSO_(4).SH_(2)O`

D

None of these

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The correct Answer is:
To identify the compound A based on the given information, we can follow these steps: ### Step-by-Step Solution: 1. **Identify the Formation of Glassy Transparent Bead:** - When compound A is heated on a platinum wire, it forms a glassy transparent bead. This is characteristic of borax (sodium tetraborate), which can be represented by the formula \( \text{Na}_2\text{B}_4\text{O}_7 \cdot 10\text{H}_2\text{O} \). - Upon heating, borax decomposes to form sodium metaborate (\( \text{NaBO}_2 \)) and boron trioxide (\( \text{B}_2\text{O}_3 \)), which are components of the glassy bead. 2. **Reaction with Copper Sulfate:** - The glassy bead formed from A reacts with copper sulfate (\( \text{CuSO}_4 \)) to produce a colored bead. This indicates that the bead contains boron, which can react with copper ions to form colored complexes. 3. **Reaction with Concentrated Sulfuric Acid and Ethanol:** - When A is treated with concentrated sulfuric acid (\( \text{H}_2\text{SO}_4 \)) and ethanol (\( \text{C}_2\text{H}_5\text{OH} \)), it produces a green flame. This is indicative of the formation of boron compounds that can emit a green flame when ignited, such as boric acid (\( \text{H}_3\text{BO}_3 \)). 4. **Alkaline Nature of Aqueous Solution:** - The aqueous solution of A is alkaline. When borax dissolves in water, it hydrolyzes to form sodium hydroxide (\( \text{NaOH} \)) and boric acid, which makes the solution alkaline. 5. **Conclusion:** - Based on the above observations, we can conclude that compound A is borax, which has the formula \( \text{Na}_2\text{B}_4\text{O}_7 \cdot 10\text{H}_2\text{O} \). ### Final Answer: The compound A is **Borax** (sodium tetraborate), with the formula \( \text{Na}_2\text{B}_4\text{O}_7 \cdot 10\text{H}_2\text{O} \). ---

To identify the compound A based on the given information, we can follow these steps: ### Step-by-Step Solution: 1. **Identify the Formation of Glassy Transparent Bead:** - When compound A is heated on a platinum wire, it forms a glassy transparent bead. This is characteristic of borax (sodium tetraborate), which can be represented by the formula \( \text{Na}_2\text{B}_4\text{O}_7 \cdot 10\text{H}_2\text{O} \). - Upon heating, borax decomposes to form sodium metaborate (\( \text{NaBO}_2 \)) and boron trioxide (\( \text{B}_2\text{O}_3 \)), which are components of the glassy bead. ...
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CENGAGE CHEMISTRY ENGLISH-QUALITATIVE INORGANIC SALT ANALYSIS-Exercises (Linked Comprehension)
  1. Identify C

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  2. Identify A

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  3. i.(A) overset(Delta)to glassy traparent beat (B) on platinum wire (...

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  4. i.(A) overset(Delta)to glassy traparent beat (B) on platinum wire (...

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  5. i.(A) overset(Delta)to glassy traparent beat (B) on platinum wire (...

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  6. i.(A) overset(Delta)to glassy traparent beat (B) on platinum wire (...

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  7. A colourless mixture of two salts (A) and (B) [excess] is soluble in H...

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  8. A colourless mixture of two salts (A) and (B) [excess] is soluble in H...

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  9. A colourless mixture of two salts (A) and (B) [excess] is soluble in H...

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  10. Find the anion (s)

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  11. Find out (E )

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  12. Find out (F)

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  13. Cations are classified into varius group on the basis of their behav...

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  14. Cations are classified into varius group on the basis of their behav...

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  15. Cations are classified into varius group on the basis of their behav...

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  16. The reagents like AgNO(3),K(4)[Fe(CN)(6)],KCNS,KI,K(2)CrO(4) Nessler's...

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  17. The reagents like AgNO(3),K(4)[fe(CN)(6)],KCNS,KI,K(2)CrO(4) Nessler's...

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  18. The reagents like AgNO(3),K(4)[Fe(CN)(6)],KCNS,KI,K(2)CrO(4) Nessler's...

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  19. NH(3) solution was added to four semple solution in difference test t...

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  20. NH(3) solution was added to four semple solution in difference test t...

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