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The brown ring test is performed for the...

The brown ring test is performed for the qualitative detection of

A

Bromides

B

Iodides

C

Nitrates

D

Nitrite

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### Step-by-Step Solution: 1. **Understanding the Brown Ring Test**: The brown ring test is a qualitative analysis method used specifically for the detection of nitrate ions (NO3⁻) in a solution. 2. **Preparation of the Test**: To perform the brown ring test, you need to prepare a solution that contains nitrate ions. This can be done by dissolving a nitrate salt in water. 3. **Adding Iron(II) Sulfate**: Once you have the nitrate solution, you will add Iron(II) sulfate (FeSO4) to the solution. This is crucial as the iron(II) ions (Fe²⁺) will react with the nitrate ions. 4. **Adding Concentrated Sulfuric Acid**: After adding Iron(II) sulfate, you must carefully add concentrated sulfuric acid (H2SO4) to the solution. It is important to add the acid slowly and without stirring to ensure that a distinct layer of sulfuric acid forms below the aqueous solution. 5. **Formation of the Brown Ring**: If nitrate ions are present in the solution, a brown ring will form at the interface of the two layers (the aqueous layer and the sulfuric acid layer). This brown ring is due to the formation of a complex known as [Fe(H2O)5NO]²⁺. 6. **Chemical Reaction**: The chemical reaction that occurs can be summarized as follows: - Nitrate ions (NO3⁻) react with Iron(II) ions (Fe²⁺) in the presence of hydrogen ions (H⁺) from sulfuric acid to form nitrogen monoxide (NO) and Iron(III) ions (Fe³⁺). - The resulting Iron(III) ions then form a complex with water and nitrogen monoxide, leading to the formation of the brown ring. 7. **Conclusion**: The brown ring test is specifically used for the qualitative detection of nitrates. Therefore, the correct answer to the question is that the brown ring test is performed for the qualitative detection of nitrates.
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CENGAGE CHEMISTRY ENGLISH-QUALITATIVE INORGANIC SALT ANALYSIS-Exercises (Multiple Correct) Part-A (Analysis Of Anions)
  1. Which of the following compounds are soluble in water ?

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  2. Which of the following halides are not soluble in water ?

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  3. The brown ring test is performed for the qualitative detection of

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  4. Which of the following salt does give positive test for nitrate ion?

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  5. Which of the following anions are easily removed from aqueous solutio...

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  6. A white ppt , is obtainned when

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  7. Which pair would not be expected to form precipitate when solution ...

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  8. Reddish brown gas is obtained when the following are treated with conc...

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  9. The correct statement (s) is/are with respect to chromy chloride test

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  10. Nitrite (NO(2)^(Θ)) interfers in the ring -test of nitrate (NO(3)^(Θ))...

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  11. If (X) turn lime water milky , then X may be

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  12. If(X) turns acidified K(2)Cr(2)O(7) solution green , then X may be

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  13. If (X) decolourises acidfied KMnO(4) solution , then X may

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  14. Which of the following ppt (s) of sulphite ion have white colour ?

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  15. Which of the following gases have brown colour ?

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  16. S^(2-) and SO(3)^(2-) can be distinguished by using

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  17. Consider the following reaction Nitrite + acetic acid + thio urea r...

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  18. The gas will be

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  19. Which of the following combinations in an aqueous medium will give a ...

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  20. Which of the following nitrates are water soluble ?

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