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Some pale green crystals are strongly h...

Some pale green crystals are strongly heated .The gases then off are passed into a container surrounded by ice and then through a solution of acidified `KMnO_(4)` The `KMnO_(4)` is decolourised, a waxy white solid is formed in the ice container, this is dissolvesd in water .The solution will

A

Give a precipitate with silver nitrate solution

B

Give a precipitate with barium chloride solution

C

Turn red litmus blue

D

Give blue colour with starch solution

Text Solution

Verified by Experts

The correct Answer is:
b

Assume green crystal of `FeSO_(4)`
`FeSO_(4) overset(Delta) to Fe_(2)O_(3) + SO_(2) + SO_(3)`
`SO_(3) + MnO_(4)^(Theta) rarr Mn^(2-) + SO_(4)^(2-)`
`SO_(3)` forms waxy white solid `(H_(2)SO_(4))` in ice container white is dissolved in water and gives `SO_(4)^(2-)` ion .When `BaCI_(2)` reacts `SO_(4)^(2+)` ion it forms ppt of `BeSO_(4)`
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CENGAGE CHEMISTRY ENGLISH-QUALITATIVE INORGANIC SALT ANALYSIS-Exercises (Single Correct) Part-A (Analysis Of Anions)
  1. A white metal sulphide soluble in water is

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  2. A salt having BO(3)^(3-) on burning with conc H(2)SO(4) gives …. edge...

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  3. KBr,on reaction with conc H(2)SO(4) give reddish brown gas which blea...

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  4. An inorganic salt when heated evolves coloured gas which bleaches moi...

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  5. The colour developed when sodium sulphide is added to sodium nitro...

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  6. Using dil HCI, which of the following radical cannot be confirmed

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  7. The solution of a chemical compound X reacts with AgNO(3) solution ...

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  8. Preparation of Na(2)CO(3) extract is made for acid radical analysis...

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  9. H(2)S and SO(2) can be distinguished by

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  10. Two test tubes containing a nitrate and a bromide are treated separat...

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  11. A colouless solution of a compound gives a precipitate with AgNO(3) so...

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  12. A white precipitate insoluble in conc HNO(3) is formed when aqueous ...

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  13. Aqueous solution of Na(2)S(2)O(3) on reaction with CI(2), gives

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  14. When CS(2) layer containing both Br(2) and I(2) is shaken with exces...

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  15. Which of the following pair of acid radicals can be distinguished b...

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  16. The aqueous solution of salt gives white ppt with lead acetate solut...

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  17. Some pale green crystals are strongly heated .The gases then off are ...

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  18. For testing sodium carbonate solution for the presence of sulphate...

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  19. Salt A overset("Layer test") to If reddish brown layer come first , t...

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  20. CaCO(3)(s) + CH(3)COOH underset(Na(2)C(2)O(4) "solution") to ? Comm...

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