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A green mass is formed in the charcoal...

A green mass is formed in the charcoal cavity test when a colourless salt `(X)` is fused with cobalt nitrate. (X) may contain

A

Aluminium

B

copper

C

Barium

D

Zinc

Text Solution

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The correct Answer is:
To solve the question regarding the formation of a green mass when a colorless salt (X) is fused with cobalt nitrate in the charcoal cavity test, we will analyze the possible components of salt (X) and the reactions involved. ### Step-by-Step Solution: 1. **Identify the Colorless Salt (X)**: The question states that the colorless salt (X) can contain aluminum, copper, barium, or zinc. We need to determine which of these metals, when fused with cobalt nitrate, will produce a green mass. 2. **Analyze Each Metal**: - **Aluminum**: When aluminum is tested in the charcoal cavity, it typically forms a blue mass. Therefore, aluminum is not the correct choice. - **Copper**: Copper, when subjected to the charcoal cavity test, produces a brown residue. Thus, copper is also not the correct choice. - **Barium**: Barium does not produce any significant reaction in the charcoal cavity test, so it can be ruled out. - **Zinc**: Zinc is a potential candidate. When zinc salts are tested, they can react with cobalt nitrate. 3. **Reactions Involved**: - When zinc sulfate (ZnSO4) is fused with sodium carbonate (Na2CO3), zinc carbonate (ZnCO3) is formed. - Zinc carbonate decomposes upon heating to form zinc oxide (ZnO) and carbon dioxide (CO2). - Cobalt nitrate (Co(NO3)2) decomposes upon heating to form cobalt oxide (CoO), nitrogen dioxide (NO2), and oxygen (O2). - The green mass is formed when cobalt oxide reacts with zinc oxide: \[ \text{CoO} + \text{ZnO} \rightarrow \text{CoZnO2} \] This compound, cobalt zinc oxide (CoZnO2), is green in color. 4. **Conclusion**: Based on the analysis, the colorless salt (X) that can produce a green mass when fused with cobalt nitrate is zinc. Therefore, the correct answer is that (X) may contain zinc. ### Final Answer: The colorless salt (X) may contain zinc. ---

To solve the question regarding the formation of a green mass when a colorless salt (X) is fused with cobalt nitrate in the charcoal cavity test, we will analyze the possible components of salt (X) and the reactions involved. ### Step-by-Step Solution: 1. **Identify the Colorless Salt (X)**: The question states that the colorless salt (X) can contain aluminum, copper, barium, or zinc. We need to determine which of these metals, when fused with cobalt nitrate, will produce a green mass. 2. **Analyze Each Metal**: ...
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