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The group II precipitate soluble in yell...

The group II precipitate soluble in yellow ammonium sulphide may be

A

`As,Sb,Sn`

B

`Ca,Hg,Bi,Cd`

C

Both (a) and (b)

D

None of these

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To solve the question regarding which Group II precipitate is soluble in yellow ammonium sulfide, we can follow these steps: ### Step-by-Step Solution: 1. **Identify Group II Cations**: The Group II cations that we need to consider include arsenic (As³⁺), bismuth (Bi³⁺), mercuric ion (Hg²⁺), copper (Cu²⁺), cadmium (Cd²⁺), tin (Sn²⁺), and antimony (Sb³⁺). 2. **Understand the Group Reagent**: The group reagent for Group II cations is a combination of dilute hydrochloric acid (HCl) and hydrogen sulfide (H₂S). This reagent helps to precipitate the sulfides of these cations. 3. **Identify Soluble Sulfides in Yellow Ammonium Sulfide**: Yellow ammonium sulfide (NH₄₂S) can dissolve certain metal sulfides. We need to determine which of the sulfides of the Group II cations are soluble in this reagent. 4. **List the Cations and Their Sulfides**: The sulfides of the cations that we are considering are: - Arsenic sulfide (As₂S₃) - Antimony sulfide (Sb₂S₃) - Tin sulfide (SnS) 5. **Check Solubility in Yellow Ammonium Sulfide**: - Arsenic sulfide (As₂S₃) is soluble in yellow ammonium sulfide. - Antimony sulfide (Sb₂S₃) is also soluble in yellow ammonium sulfide. - Tin sulfide (SnS) is soluble in yellow ammonium sulfide. 6. **Conclusion**: Based on the solubility of the sulfides in yellow ammonium sulfide, the cations whose sulfides are soluble are arsenic, antimony, and tin. ### Final Answer: The Group II precipitate soluble in yellow ammonium sulfide may be arsenic, antimony, and tin.

To solve the question regarding which Group II precipitate is soluble in yellow ammonium sulfide, we can follow these steps: ### Step-by-Step Solution: 1. **Identify Group II Cations**: The Group II cations that we need to consider include arsenic (As³⁺), bismuth (Bi³⁺), mercuric ion (Hg²⁺), copper (Cu²⁺), cadmium (Cd²⁺), tin (Sn²⁺), and antimony (Sb³⁺). 2. **Understand the Group Reagent**: ...
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CENGAGE CHEMISTRY ENGLISH-QUALITATIVE INORGANIC SALT ANALYSIS-Exercises (Single Correct) Part-C (Analysis Of Cations)
  1. As(2)S(3) is

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  2. A black sulphide is formed by the action of H(2)S on

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  3. The group II precipitate soluble in yellow ammonium sulphide may be

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  4. Dolute nitric acid is generally not used for the preparation of origin...

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  5. The sulphide not soluble in hot dilute nitric acid is

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  6. H(2)S will precipitate the sulphide of all the metals from the soluti...

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  7. To a solution of a substance gradual addition of ammonium hydroxide ...

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  8. A compound is soluble in water. If ammonia is added to aqueous solutio...

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  9. A light green coloured salt soluble in water gives black percipitate o...

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  10. All ammonium salts liberate ammonia when :

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  11. Manganese salt + PbO(2) + conc. HNO(2) rarr The solution has purple ...

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  12. An orange precipitate of group II is dissolve in conc HCI the solutio...

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  13. Which of the following solution gives precipitate with Pb(NO(3))(2) bu...

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  14. A white powder when strongly heated gives off brown fumes. A solutio...

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  15. The ion that cannot be precipitate by both HCI and H(2)S is

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  16. The presence of magnesium is confimed in the qualitative analysis by t...

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  17. In qualitative inorganic analysis phosphate , if present, is to be eli...

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  18. Na(2)CO(3) cannot be used in place of (NH(4))(2)CO(3) for the precipit...

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  19. Disodium hydrogen phosphate is used to test :

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  20. Reddish - brown (chocolate ) ppt. is formed with :

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