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Precipitation of Cd^(2+) and Cu^(2+) tak...

Precipitation of `Cd^(2+)` and `Cu^(2+)` takes place in presence of (a)____by (b)____.

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To solve the question regarding the precipitation of `Cd^(2+)` and `Cu^(2+)`, we will follow these steps: ### Step-by-Step Solution: 1. **Identify the Ions**: The ions we are dealing with are `Cd^(2+)` (Cadmium ion) and `Cu^(2+)` (Copper ion). Both of these ions are part of the same group in the periodic table, specifically group 2 of the cations. 2. **Determine the Precipitating Agent**: To precipitate these ions, we need to identify a suitable precipitating agent. In qualitative inorganic analysis, `HCl` (Hydrochloric acid) is commonly used to create an acidic environment that allows for the precipitation of certain metal ions. 3. **Use of H2S**: The actual precipitation of `Cd^(2+)` and `Cu^(2+)` occurs when we introduce `H2S` (Hydrogen sulfide) gas. `H2S` reacts with the metal ions to form insoluble sulfides. 4. **Write the Precipitation Reactions**: - For Cadmium: \[ \text{Cd}^{2+} + \text{S}^{2-} \rightarrow \text{CdS (s)} \quad \text{(Cadmium sulfide precipitate)} \] - For Copper: \[ \text{Cu}^{2+} + \text{S}^{2-} \rightarrow \text{CuS (s)} \quad \text{(Copper sulfide precipitate)} \] 5. **Final Answer**: Therefore, the precipitation of `Cd^(2+)` and `Cu^(2+)` takes place in presence of **dilute HCl** by **H2S gas**. ### Summary: - The final answer to fill in the blanks is: - (a) dilute HCl - (b) H2S gas
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CENGAGE CHEMISTRY ENGLISH-QUALITATIVE INORGANIC SALT ANALYSIS-Exercises (Fill In The Blanks)
  1. PbCl(2) is soluble in (a) . AgCl is soluble in (b) white Hg(2)Cl(2) i...

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  2. Cd^(2+) and Cu^(2+) are seprated by (a) formation using (b) in which ...

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  3. Precipitation of Cd^(2+) and Cu^(2+) takes place in presence of (a)by ...

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  4. NH(4)Cl is added along with NH(4)OH in group (a)to (b) concentration o...

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  5. Separation of basic radicals is based on (a) and (b) .

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  6. Gas that turns lime water milky and aciddied K(2)Cr(2)O(7) green is...

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  7. NH(4)SCN gives red colour with (s) due to the formation of (b) .

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  8. HgCl(2) gives orange ppt , with (a) , which dissolves in excess of i...

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  9. Al(OH)(3) is precipitate if its produces (a)is (b) that K(sp)

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  10. PbSO(4) is soluble in (a) due to formation of (b) .

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  11. A reagent that can detect any of Cu^(2+),Fe^(3+),Zn^(2+) and Cd^(2+) i...

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  12. Fe^(2+) gives blue coloue, called(a) with (b)white Fe^(2+) gives blue ...

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  13. Ferric alum is the indicator in the titration of Ag^(o+) with SCN^(Θ)...

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  14. FeC(2)O(4) can decolorise acidified KMnO(4) due to the oxidation of (...

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  15. Acidified KMnO(4) can be decolourised by (a).

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  16. Iron (II)sulphide gives foul smell of (a).

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  17. AgBr is soluble in hypo forming (a) .

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  18. NO(3)^(Θ) is detected by (a) when (b)is formed on the addition of FeS...

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  19. CI^(Θ)is confirmed by (a) .

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  20. Addition of one drop of HNO(3) in group (III) analysis is to (a) .

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